| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Hriljac, Joseph, A.
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (17/17 displayed)
- 2023One-pot synthesis of superparamagnetically modified zeolite chabazite for removal of Cs<sup>+</sup> from radioactively contaminated watercitations
- 2021Evolution of the Local Structure in the Sol-Gel Synthesis of Fe3C Nanostructurescitations
- 2020Nuclear wastewater decontamination by 3D printed hierarchical zeolite monolithscitations
- 2018Derivation of Transferable Pair Potentials and the Calculation of Intrinsic Defect Properties for Xenotimecitations
- 2018Transformation of Cs-IONSIV ® into a ceramic wasteform by hot isostatic pressingcitations
- 2016A Potential Wasteform for Cs Immobilizationcitations
- 2013Thermal Conversion of Cs-exchanged IONSIV IE-911 into a Novel Caesium Ceramic Wasteform by Hot Isostatic Pressingcitations
- 2012Pair distribution function-derived mechanism of a single-crystal to disordered to single-crystal transformation in a hemilabile metal–organic frameworkcitations
- 2012The effect of extra framework species on the intrinsic negative thermal expansion property of zeolites with the LTA topology.citations
- 2011Enhanced stability and local structure in biologically relevant amorphous materials containing pyrophosphatecitations
- 2010Synthesis and structural characterisation using Rietveld and pair distribution function analysis of layered mixed titanium-zirconium phosphatescitations
- 2009Comparison of structural, microstructural, and electrical analyses of barium strontium titanate thin filmscitations
- 2007Hydrostatic low-range pressure applications of the Paris-Edinburgh cell utilizing polymer gaskets for diffuse X-ray scattering measurementscitations
- 2005Pillared clays as catalysts for hydrocracking of heavy liquid fuelscitations
- 2002Pressure-induced volume expansion of zeolites in the Natrolite familycitations
- 2002Oxygen-stabilised partial amorphization in a Zr₅₀Cu₅₀ alloycitations
- 2001Crystallisation of oxygen-stabilised amorphous phase in a Zr50Cu50 alloycitations
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article
Pair distribution function-derived mechanism of a single-crystal to disordered to single-crystal transformation in a hemilabile metal–organic framework
Abstract
Flexible metal–organic frameworks (MOFs) are materials of great current interest. A small class of MOFs show flexibility driven by reversible bonding rearrangements that lead directly to unusual properties. Cu-SIP-3 is a MOF based on the 5-sulfoisophthalate ligand, where the strong copper–carboxylate bonds ensure that the three-dimensional integrity of the structure is retained while allowing bonding changes to occur at the more weakly bonding sulfonate group leading to unusual properties such as the ultra-selective adsorption of only certain gases. While the integrity of the framework remains intact during bonding changes, crystalline order is not retained at all times during the transformations. X-Ray diffraction reveals that highly crystalline single crystals lose order during the transformation before regaining crystallinity once it is complete. Here we show how X-ray pair distribution function analysis can be used to reveal the mechanism of the transformations in Cu-SIP-3, identifying the sequence of atomic displacements that occur in the disordered phase. A similar approach reveals the underlying mechanism of Cu-SIP-3's ultra-selective gas adsorption.