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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Daniel, Christophe
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Publications (7/7 displayed)
- 2023Extended <i>Q</i>-range small-angle neutron scattering to understand the morphology of proton-exchange membranes: the case of the functionalized syndiotactic-polystyrene model systemcitations
- 2023Extended Q -range small-angle neutron scattering to understand the morphology of proton-exchange membranes: the case of the functionalized syndiotactic-polystyrene model systemcitations
- 2022Tailoring novel polymer/UTSA-16 hybrid aerogels for efficient CH4/CO2 separationcitations
- 2012Monolithic nanoporous-crystalline aerogels based on PPOcitations
- 2011Nanoporous crystalline phases of poly(2,6-dimethyl-1,4-phenylene)oxidecitations
- 2011Aerogels and polymorphism of isotactic poly(4-methyl-pentene-1)citations
- 2010Hydrogen adsorption by δ and ε crystalline phases of syndiotactic polystyrene aerogelscitations
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article
Monolithic nanoporous-crystalline aerogels based on PPO
Abstract
Monolithic and robust aerogels exhibiting nanoporous-crystalline modifications of an industrially relevant polymer (poly(2,6-dimethyl-1,4-phenylene)oxide, generally known as polyphenyleneoxide, PPO), have been obtained from thermoreversible gels, by sudden solvent extraction with supercritical carbon dioxide. The aerogel formation occurs only in the presence of semicrystalline nanofibrils of syndiotactic polystyrene, a polymer presenting molecular miscibility with PPO in the amorphous phase. These mixed monolithic aerogels can present nanoporous-crystalline phases of both polymers and hence are very promising for water and air purification. For instance, the carbon tetrachloride uptake from 10 ppm aqueous solutions can be as high as 19 wt%.