| People | Locations | Statistics |
|---|---|---|
| Naji, M. |
| |
| Motta, Antonella |
| |
| Aletan, Dirar |
| |
| Mohamed, Tarek |
| |
| Ertürk, Emre |
| |
| Taccardi, Nicola |
| |
| Kononenko, Denys |
| |
| Petrov, R. H. | Madrid |
|
| Alshaaer, Mazen | Brussels |
|
| Bih, L. |
| |
| Casati, R. |
| |
| Muller, Hermance |
| |
| Kočí, Jan | Prague |
|
| Šuljagić, Marija |
| |
| Kalteremidou, Kalliopi-Artemi | Brussels |
|
| Azam, Siraj |
| |
| Ospanova, Alyiya |
| |
| Blanpain, Bart |
| |
| Ali, M. A. |
| |
| Popa, V. |
| |
| Rančić, M. |
| |
| Ollier, Nadège |
| |
| Azevedo, Nuno Monteiro |
| |
| Landes, Michael |
| |
| Rignanese, Gian-Marco |
|
Madsen, Frederikke Bahrt
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (39/39 displayed)
- 2024Permeation-Enhancing Strategies for Transdermal Delivery of Cannabinoidscitations
- 2023Antimicrobial silicone skin adhesives facilitated by controlled octenidine release from glycerol compartmentscitations
- 2022A reliable quantitative method for determining CBD content and release from transdermal patches in Franz cellscitations
- 2021Glycerol‐Filled Silicone Adhesive Patches with Excellent Sun Protectioncitations
- 2019Glycerol-silicone foams - Tunable 3-phase elastomeric porous materialscitations
- 2018Degradation patterns of silicone-based dielectric elastomers in electrical fieldscitations
- 2016Silicone elastomers with superior softness and dielectric properties
- 2016Bimodal condensation silicone elastomers as dielectric elastomers
- 2016Self-Healing, High-Permittivity Silicone Dielectric Elastomercitations
- 2016A simple method for reducing inevitable dielectric loss in high-permittivity dielectric elastomerscitations
- 2016The Current State of Silicone-Based Dielectric Elastomer Transducerscitations
- 2016Molecular beam deposition of high-permittivity polydimethylsiloxane for nanometer-thin elastomer films in dielectric actuatorscitations
- 2016Molecular beam deposition of high-permittivity polydimethylsiloxane for nanometer-thin elastomer films in dielectric actuatorscitations
- 2016Mechanically compliant electrodes and dielectric elastomers from PEG-PDMS copolymers
- 2016Mechanical and Electrical Ageing Effects on the Long-Term Stretching of Silicone Dielectric Elastomers with Soft Fillers:Long-Term Stretching of Silicone Dielectric Elastomerscitations
- 2015A new soft dielectric silicone elastomer matrix with high mechanical integrity and low lossescitations
- 2015Super soft silicone elastomers with high dielectric permittivitycitations
- 2015High energy density interpenetrating networks from ionic networks and siliconecitations
- 2015Dielectric elastomers, with very high dielectric permittivity, based on silicone and ionic interpenetrating networkscitations
- 2015Functional silicone elastomers via novel siloxane copolymers and chain extenders
- 2015Functional silicone copolymers and elastomers with high dielectric permittivity
- 2015Silicone chain extender
- 2015Soft Functional Silicone Elastomers with High Dielectric Permittivty: Simple Additives vs. Cross-Linked Synthesized Copolymers
- 2015Silicone elastomers with high dielectric permittivity and high dielectric breakdown strength based on tunable functionalized copolymerscitations
- 2014Synthetic Strategies for High Dielectric Constant Silicone Elastomers
- 2014Synthetic Strategies for High Dielectric Constant Silicone Elastomers
- 2014Silicone elastomers with high dielectric permittivity and high dielectric breakdown strength based on dipolar copolymerscitations
- 2013Novel silicone compatible cross-linkers for controlled functionalization of PDMS networkscitations
- 2013Novel cross-linkers for PDMS networks for controlled and well distributed grafting of functionalities by click chemistrycitations
- 2013Silicone resembling poly (propylene glycol) interpenetrating networks based on no pre-stretch as basis for electrical actuatorscitations
- 2013Dipolar cross-linkers for PDMS networks with enhanced dielectric permittivity and low dielectric losscitations
- 2013Intelligente materialer som kunstige muskler og energi-høstere
- 2013Development of novel PDMS elastomers for dielectric electroactive polymers (DEAPs)
- 2012New Cross-linkers for PDMS Networks
- 2012Development of new PDMS based materials for dielectric electroactive polymers (DEAPs) as actuators and generators
- 2012Udvikling af materialer til kunstige muskler
- 2012Novel silicone compatible cross-linkers for controlled and well distributed functionalization of PDMS networks
- 2012Bimodal Networks as Candidates for Electroactive Polymers
- 2011New Cross-linkers for PDMS Networks
Places of action
| Organizations | Location | People |
|---|
article
Novel cross-linkers for PDMS networks for controlled and well distributed grafting of functionalities by click chemistry
Abstract
An azide-containing, trifunctional vinyl cross-linker for silicone networks has been synthesized. The cross-linker has through Cu(i) catalyzed 1,3-cycloaddition been reacted with six different alkyne-containing chemical groups which each possess a particular functionality. The functional cross-linkers have been utilized to prepare novel polydimethylsiloxane (PDMS) networks. All functional cross-linkers were successfully incorporated into the networks and were demonstrated to be well distributed within the PDMS films. This was substantiated by fluorescence microscopy of a film prepared with the 4-methyl-umbelliferone containing cross-linker. TGA showed that a ferrocene functionality increased the thermal degradation temperature of PDMS. It was furthermore shown that the incorporation of only 0.25 wt% of the push-pull dipole, ethynyl-4-nitrobenzene, increased the dielectric permittivity of PDMS by 35%. The contact angle of PDMS films was increased from 108° to 116° by the introduction of a small poly(pentafluorostyrene) chain. Finally, 17α-ethynyl-1,3,5(10)-estratriene-3,17β-diol and 1-ethynyl-3,5- bis(trifluoromethyl)benzene were incorporated as examples of other functional groups. © 2013 The Royal Society of Chemistry.