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Kanibolotskyy, Oleksandr
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Publications (8/8 displayed)
- 2014Field effect mobility, morphology and electroluminescence of a semiconductor based on a DPP-quaterfluorene quadrupolar linear conjugated systemcitations
- 2013Highly-photostable and mechanically flexible all-organic semiconductor laserscitations
- 2012Electrochromic properties of a poly(dithienylfuran) derivative featuring a redox-active dithiin unitcitations
- 2010Amplified spontaneous emission in free-standing membranes incorporating star-shaped monodisperse π-conjugated truxene oligomerscitations
- 2009Free-standing light-emitting organic nanocomposite membranes
- 2009Star-shaped oligofluorene nanostructured blend materialscitations
- 2009Hybrid GaN/organic microstructured light-emitting devices via ink-jet printingcitations
- 2007The role of functional nitro and cyano groups in the self-assembly of 1,3-dithiole-2-thione-halogen adductscitations
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article
Electrochromic properties of a poly(dithienylfuran) derivative featuring a redox-active dithiin unit
Abstract
<p>A teraryl monomer containing a 1,4-dithiin-furan central unit has been synthesised and characterised by single crystal X-ray crystallography. The di(thienyl)furan monomer 11 was successfully polymerised electrochemically and shown to possess a lower electrochemical band gap than its terthiophene analogue (1.97 eV cf. 2.11 eV). The electrochromic properties of this polymer proved to be superior to PEDOT, with fast switching and reversible colour transformation at high colour contrast (CE = 212 cm(2) C-1 cf. 183 cm(2) C-1 for PEDOT at 95% optical switch).</p>