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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Seo, Jin Won
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (16/16 displayed)
- 2020Nitrogen doped carbon aerogel composites with TiO2 and ZnO prepared by atomic layer depositioncitations
- 2017Inducing conductivity in immiscible PS/PP blends by a percolated polyaniline/PA filler selectively localised by specific interactions
- 2017A novel direct liquid injection low pressure chemical vapor deposition system (DLI-LPCVD) for the deposition of thin films
- 2017Carbon nanotube-grafted carbon fiber polymer composites: Damage characterization on the micro-scale
- 2017Tuning the phase separated morphology and resulting electrical conductivity of carbon nanotube filled PαMSAN/PMMA blends by compatibilization with a random or block copolymercitations
- 2016Liquid nickel salts: synthesis, crystal structure determination and electrochemical synthesis of nickel nanoparticles
- 2016Auger electron spectroscopy study of semiconductor surfaces: Effect of cleaning in inert atmosphere
- 2014Analysis of the variation in nanohardness of pearlitic steel: Influence of the interplay between ferrite crystal orientation and cementite morphologycitations
- 2012Single Crystalline GeSn On Silicon By Solid Phase Crystallization
- 2012Stability of sputter-deposited gold nanoparticles in imidazolium ionic liquidscitations
- 2011Growth of sputter-deposited gold nanoparticles in ionic liquidscitations
- 2011Spacious and mechanically flexible mesoporous silica thin film composed of an open network of interlinked nanoslabscitations
- 2010Sputtering of Nanoparticles in/on Ionic Liquids
- 2010Layering in ionic liquids
- 2006Structural domains in antiferromagnetic LaFeO3 thin films ; Special issue on the occasion of the 65th birthday of Prof. K. Urban
- 2002Controlled Growth and Applications of Carbon Nanotubescitations
Places of action
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article
Stability of sputter-deposited gold nanoparticles in imidazolium ionic liquids
Abstract
The stability of gold nanoparticles synthesised by sputter deposition has been studied in situ in 1-butyl-3-methylimidazolium ionic liquids with bis(trifluoromethylsulfonyl) imide, tetrafluoroborate, hexafluorophosphate and dicyanamide anions with UV-VIS absorption spectroscopy and transmission electron microscopy. Besides the growth of the gold nanoparticles, two other processes were observed after sputtering, namely aggregation and sedimentation of these nanoparticles. To model the absorption spectra of the sputtered gold nanoparticles, generalized multiparticle Mie calculations were performed. These theoretical calculations confirm the increase in absorbance at longer wavelength for larger aggregates and are in agreement with the experimental observations. It was found that the kinetics of aggregation and sedimentation scale with the viscosity of the ionic liquid. Small amounts of water were found to have a large detrimental influence on the stability of the colloidal suspensions of the gold nanoparticles in ionic liquids. From the large discrepancy between the theoretical and the experimentally observed stability of the NPs, it was concluded that structural forces stabilize the gold nanoparticles. This was also borne out by AFM measurements. ; status: published