| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Ros, Josep
Universitat Autònoma de Barcelona
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (16/16 displayed)
- 2021Preparation and characterization of nanoparticle-doped polymer inclusion membranescitations
- 2021Preparation and Characterization of Nanoparticle-Doped Polymer Inclusion Membranes: Application to the Removal of Arsenate and Phosphate from Waterscitations
- 2018Tailoring the Synthesis of LnF3 (Ln = La–Lu and Y) Nanocrystals via Mechanistic Study of the Coprecipitation Method
- 2018Epitaxial YBa2Cu3O7−x nanocomposite films and coated conductors from BaMO3 (M = Zr, Hf) colloidal solutions
- 2016Unique nanostructural features in Fe, Mndoped YBCO thin filmscitations
- 2016Ultra- fast microwave-assisted reverse microemulsion synthesis of Fe3O4@SiO2 core–shell nanoparticles as a highly recyclable silver nanoparticle catalytic platform in the reduction of 4- nitroanilinecitations
- 2013Study of new metallomacrocyclic Pd(ii) complexes based on hybrid pyrazole sulfoxide/sulfone ligands and their contribution to supramolecular networkscitations
- 2011Variable behaviour of flexible N,O-mixed pyrazole ligand towards Zn(ii), Cd(ii) and Hg(ii) ions. Synthesis, crystal structure and fluorescent propertiescitations
- 2010Synthesis, X-ray crystal structure and NMR characterisation of mononuclear Pd(II) and Pt(II) complexes of didentate ligands with NN′-donor setcitations
- 2010Synthesis and characterization of new N-alkylamino-3,5-diphenylpyrazole ligands and reactivity toward PdII and PtII. Study of the cis-trans isomerizationcitations
- 2009Reactivity of [PdCl(bdtp)](BF4) with monodentate neutral and anionic ligands. Structure of [Pd(bdtp)(PPh3)](BF4)2 (bdtp = 1,5-bis(3,5-dimethyl-1-pyrazolyl)-3-thiapentane)citations
- 2008Synthesis, characterization and X-ray crystal structure determination of cyclopalladated [Csp2,N,N′]-, zwitterionic and chelated compounds in the reaction of 3,5-diphenyl-N-alkylaminopyrazole derived ligands with Pd(II)citations
- 2007Preparation and structural characterisation of a Cd(II) complex with unusual geometrycitations
- 2006Synthesis of new palladium(II) compounds with several bidentate nitrogen-donor ligands: Structural analyses by 1H and 13C{1H} NMR spectroscopy and crystal structurescitations
- 2003Synthesis, X-ray crystal structure, and NMR characterisation of thiolate-bridged dinuclear Ni(II), Pd(II) and Pt(II) complexes of didentate ligands with NS-donor setcitations
- 2003Synthesis, characterisation, and X-ray crystal structure of new Ni II, PdII, and PtII complexes of tridentate pyrazole-based ligands with an NOS-donor setcitations
Places of action
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article
Study of new metallomacrocyclic Pd(ii) complexes based on hybrid pyrazole sulfoxide/sulfone ligands and their contribution to supramolecular networks
Abstract
Treatment of the pyrazole sulfoxide, 1,1′-(2,2′- sulfoneinylbis(ethanediyl))bis(3,5-dimethyl-1-pyrazole) (L1), and pyrazole sulfone, 1,1′-(2,2′-sulfoneonylbis(ethanediyl))bis(3,5-dimethyl-1- pyrazole) (L2) ligands, with [PdCl<inf>2</inf>(CH<inf>3</inf>CN)<inf>2</inf>] in a 1:1 M:L ratio, yields two kinds of complexes, monomer or dimer, depending on the solvent of the reaction. Monomeric complexes [PdCl<inf>2</inf>(L)] (L = L1 (1) or L2 (3)) are obtained when the solvent is acetonitrile, whereas when the reaction takes place in tetrahydrofuran, dimeric complexes [PdCl <inf>2</inf>(L)]<inf>2</inf> (L = L1 (2) or L2 (4)) are obtained. Diffusion NMR studies have been performed to characterize a mixture of the monomeric/dimeric species in CD<inf>3</inf>CN solution. The solid-state structures of 3 and 4 have been determined by single-crystal X-ray diffraction methods. The extended structures allowed the study of the effects of the structure of the ligands on the topology and interpenetration form (two-dimensional layer polymers and three-dimensional networks). Finally, it has been observed that dimers are converted into the corresponding monomers under continuous acetonitrile reflux conditions, thus indicating that the latter are thermodynamically more stable than dimers. © The Royal Society of Chemistry.