| People | Locations | Statistics |
|---|---|---|
| Naji, M. |
| |
| Motta, Antonella |
| |
| Aletan, Dirar |
| |
| Mohamed, Tarek |
| |
| Ertürk, Emre |
| |
| Taccardi, Nicola |
| |
| Kononenko, Denys |
| |
| Petrov, R. H. | Madrid |
|
| Alshaaer, Mazen | Brussels |
|
| Bih, L. |
| |
| Casati, R. |
| |
| Muller, Hermance |
| |
| Kočí, Jan | Prague |
|
| Šuljagić, Marija |
| |
| Kalteremidou, Kalliopi-Artemi | Brussels |
|
| Azam, Siraj |
| |
| Ospanova, Alyiya |
| |
| Blanpain, Bart |
| |
| Ali, M. A. |
| |
| Popa, V. |
| |
| Rančić, M. |
| |
| Ollier, Nadège |
| |
| Azevedo, Nuno Monteiro |
| |
| Landes, Michael |
| |
| Rignanese, Gian-Marco |
|
Guerrero, Miguel
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (14/14 displayed)
- 2017Carborane bis-pyridylalcohols as linkers for coordination polymers : synthesis, crystal structures and guest-framework dependent mechanical propertiescitations
- 2017Unraveling the origin of magnetism in mesoporous Cu-doped SnOâ‚‚ magnetic semiconductorcitations
- 2017Voltage-induced coercivity reduction in nanoporous alloy films : a boost towards energy-efficient magnetic actuationcitations
- 2016Carborane bis-pyridylalcohols as linkers for coordination polymers: Synthesis, crystal structures, and guest-framework dependent mechanical propertiescitations
- 2016Fabricació de microrobots magnètics per al tractament d'aigües residuals
- 2016Synthesis and characterization of Pd(II), Pt(II), Cu(I), Ag(I) and Cu(II) complexes with N,O-hybrid pyrazole ligandcitations
- 2016Room-temperature synthesis of three-dimensional porous ZnO@CuNi hybrid magnetic layers with photoluminescent and photocatalytic propertiescitations
- 2016Toward uniform electrodeposition of magnetic Co-W mesowires arrays : direct versus pulse current depositioncitations
- 2015Nanomechanical behavior of 3D porous metal-ceramic nanocomposite Bi/Bi2 O3 filmscitations
- 2015New binuclear copper(II) coordination polymer based on mixed pyrazolic and oxalate ligands: structural characterization and mechanical propertiescitations
- 2015New binuclear copper(ii) coordination polymer based on mixed pyrazolic and oxalate ligands : Structural characterization and mechanical propertiescitations
- 2013White-light photoluminescence and photoactivation in cadmium sulfide embedded in mesoporous silicon dioxide templates studied by confocal laser scanning microscopycitations
- 2013Study of new metallomacrocyclic Pd(ii) complexes based on hybrid pyrazole sulfoxide/sulfone ligands and their contribution to supramolecular networkscitations
- 2011Variable behaviour of flexible N,O-mixed pyrazole ligand towards Zn(ii), Cd(ii) and Hg(ii) ions. Synthesis, crystal structure and fluorescent propertiescitations
Places of action
| Organizations | Location | People |
|---|
article
Study of new metallomacrocyclic Pd(ii) complexes based on hybrid pyrazole sulfoxide/sulfone ligands and their contribution to supramolecular networks
Abstract
Treatment of the pyrazole sulfoxide, 1,1′-(2,2′- sulfoneinylbis(ethanediyl))bis(3,5-dimethyl-1-pyrazole) (L1), and pyrazole sulfone, 1,1′-(2,2′-sulfoneonylbis(ethanediyl))bis(3,5-dimethyl-1- pyrazole) (L2) ligands, with [PdCl<inf>2</inf>(CH<inf>3</inf>CN)<inf>2</inf>] in a 1:1 M:L ratio, yields two kinds of complexes, monomer or dimer, depending on the solvent of the reaction. Monomeric complexes [PdCl<inf>2</inf>(L)] (L = L1 (1) or L2 (3)) are obtained when the solvent is acetonitrile, whereas when the reaction takes place in tetrahydrofuran, dimeric complexes [PdCl <inf>2</inf>(L)]<inf>2</inf> (L = L1 (2) or L2 (4)) are obtained. Diffusion NMR studies have been performed to characterize a mixture of the monomeric/dimeric species in CD<inf>3</inf>CN solution. The solid-state structures of 3 and 4 have been determined by single-crystal X-ray diffraction methods. The extended structures allowed the study of the effects of the structure of the ligands on the topology and interpenetration form (two-dimensional layer polymers and three-dimensional networks). Finally, it has been observed that dimers are converted into the corresponding monomers under continuous acetonitrile reflux conditions, thus indicating that the latter are thermodynamically more stable than dimers. © The Royal Society of Chemistry.