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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Briscoe, Wuge H.
University of Bristol
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (27/27 displayed)
- 2022Interfacial complexation of a neutral amphiphilic ‘tardigrade’ co-polymer with a cationic surfactant
- 2022Interfacial complexation of a neutral amphiphilic ‘tardigrade’ co-polymer with a cationic surfactant: Transition from synergy to competitioncitations
- 2022Interfacial complexation of a neutral amphiphilic ‘tardigrade’ co-polymer with a cationic surfactant: Transition from synergy to competitioncitations
- 2022Interfacial complexation of a neutral amphiphilic ‘tardigrade’ co-polymer with a cationic surfactant:Transition from synergy to competition
- 2021Heads or tails:Nanostructure and molecular orientations in organised erucamide surface layerscitations
- 2021Friction at nanopillared polymer surfaces beyond Amontons' laws:Stick-slip amplitude coefficient (SSAC) and multiparametric nanotribological propertiescitations
- 2021Friction at nanopillared polymer surfaces beyond Amontons' lawscitations
- 2021Heads or tailscitations
- 2020Mixed liposomes containing gram-positive bacteria lipidscitations
- 2020Interactions between PAMAM dendrimers and DOPC lipid multilayerscitations
- 2020Synergy, competition, and the “hanging” polymer layer:Interactions between a neutral amphiphilic ‘tardigrade’ comb co-polymer with an anionic surfactant at the air-water interfacecitations
- 2020Synergy, competition, and the “hanging” polymer layer: Interactions between a neutral amphiphilic ‘tardigrade’ comb co-polymer with an anionic surfactant at the air-water interfacecitations
- 2020Multiscale characterisation of single synthetic fibres:Surface morphology and nanomechanical propertiescitations
- 2020Interactions between PAMAM dendrimers and DOPC lipid multilayers:Membrane thinning and structural disordercitations
- 2019Bénard-Marangoni Dendrites upon Evaporation of a Reactive ZnO Nanofluid Dropletcitations
- 2018Surface structure of few layer graphenecitations
- 2017Interfacial and structural characteristics of polyelectrolyte multilayers used as cushions for supported lipid bilayerscitations
- 2016Influence of solvent polarity on the structure of drop-cast electroactive tetra(aniline)-surfactant thin filmscitations
- 2016Influence of solvent polarity on the structure of drop-cast electroactive tetra(aniline)-surfactant thin filmscitations
- 2016Structure of lipid multilayerscitations
- 2016Structure of lipid multilayers:Via drop casting of aqueous liposome dispersionscitations
- 2016Hydrophilic nanoparticles stabilising mesophase curvature at low concentration but disrupting mesophase order at higher concentrationscitations
- 2016Stability of polymersomes prepared by size exclusion chromatography and extrusioncitations
- 2014In situ X-ray reflectivity studies of molecular and molecular-cluster intercalation within purple membrane filmscitations
- 2014In situ X-ray reflectivity studies of molecular and molecular-cluster intercalation within purple membrane filmscitations
- 2011Lamellar nanocomposite films of purple membrane and poly(acrylate)
- 2010Assembly of poly(methacrylate)/purple membrane lamellar nanocomposite films by intercalation and in situ polymerisationcitations
Places of action
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article
Assembly of poly(methacrylate)/purple membrane lamellar nanocomposite films by intercalation and in situ polymerisation
Abstract
Thin films comprising ordered stacks of purple membrane (PM) sheets containing the light-driven proton pump bacteriorhodopsin (BR) were infiltrated with methacrylic acid (MA) monomers to produce lamellar bionanocomposites. Subsequent in situ polymerization and crosslinking of the guest MA molecules resulted in partially intercalated poly(methacrylate)/PM freestanding films, which showed increased stability in water, structural integrity and enhanced resistance to ethanol degradation compared with PM control films or non-polymerized MA/PM layered nanocomposites. Studies on photocycle kinetics confirmed that the polymerized PM films were functionally active, and showed an increase in the lifetime for the M-state intermediate of the photocycle. The results indicate that nanometre-thin layers of crosslinked poly(methacrylate) can be synthesized in situ between the PM sheets to produce novel functional bionanocomposites with proton transfer and photochromic properties.