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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Collins, Andrew
University of Southampton
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (8/8 displayed)
- 2010Assembly of poly(methacrylate)/purple membrane lamellar nanocomposite films by intercalation and in situ polymerisationcitations
- 2007Effects of single SNPs, haplotypes, and whole-genome LD maps on accuracy of association mappingcitations
- 2007Fine-scale linkage disequilibrium mapping of age-related macular degeneration in the complement factor H gene regioncitations
- 2005The optimal measure of linkage disequilibrium reduces error in association mapping of affection statuscitations
- 2005Polymorphisms in a disintegrin and metalloprotease 33 (ADAM33) predict impaired early-life lung functioncitations
- 2003Haplotypic analysis of the MMP-9 gene in relation to coronary artery diseasecitations
- 2003Positional cloning by linkage disequilibriumcitations
- 2002Mapping quantitative effects of oligogenes by allelic associationcitations
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article
Assembly of poly(methacrylate)/purple membrane lamellar nanocomposite films by intercalation and in situ polymerisation
Abstract
Thin films comprising ordered stacks of purple membrane (PM) sheets containing the light-driven proton pump bacteriorhodopsin (BR) were infiltrated with methacrylic acid (MA) monomers to produce lamellar bionanocomposites. Subsequent in situ polymerization and crosslinking of the guest MA molecules resulted in partially intercalated poly(methacrylate)/PM freestanding films, which showed increased stability in water, structural integrity and enhanced resistance to ethanol degradation compared with PM control films or non-polymerized MA/PM layered nanocomposites. Studies on photocycle kinetics confirmed that the polymerized PM films were functionally active, and showed an increase in the lifetime for the M-state intermediate of the photocycle. The results indicate that nanometre-thin layers of crosslinked poly(methacrylate) can be synthesized in situ between the PM sheets to produce novel functional bionanocomposites with proton transfer and photochromic properties.