| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Bund, Andreas
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (23/23 displayed)
- 2024A Novel Method for Preparation of Al–Ni Reactive Coatings by Incorporation of Ni Nanoparticles into an Al Matrix Fabricated by Electrodeposition in AlCl<sub>3</sub>:1‐Eethyl‐3‐Methylimidazolium Chloride (1.5:1) Ionic Liquid Containing Ni Nanoparticles
- 2024Integration of Multijunction Absorbers and Catalysts for Efficient Solar‐Driven Artificial Leaf Structures: A Physical and Materials Science Perspectivecitations
- 2023Analysis of Pre-Treatment Processes to Enable Electroplating on Nitrided Steel
- 2023Electrochemical reduction of tantalum and titanium halides in 1-butyl-1-methylpyrrolidinium bis (trifluoromethyl-sulfonyl)imide and 1-butyl-1-methylpyrrolidinium trifluoromethanesulfonate ionic liquids
- 2023Quasi-in-Situ Analysis of Electropolished Additively Manufactured Stainless Steel Surfaces
- 2022Hollow platinum-gold and palladium-gold nanoparticles: synthesis and characterization of composition-structure relationshipcitations
- 2022Corrosion Properties of Ni-P-B Dispersion Coating for Industrial Knives and Bladescitations
- 2022Selective Metallization of Polymers: Surface Activation of Polybutylene Terephthalate (PBT) Assisted by Picosecond Laser Pulsescitations
- 2021Selective metallization of polymers: surface activation of polybutylene terephthalate (PBT) assisted by picosecond laser pulsescitations
- 2021The need for digitalisation in electroplating – How digital approaches can help to optimize the electrodeposition of chromium from trivalent electrolytes
- 2021Anti-corrosive siloxane coatings for improved long-term performance of supercapacitors with an aqueous electrolytecitations
- 2021Analysis of the physical and photoelectrochemical properties of c-Si(p)/a-SiC:H(p) photocathodes for solar water splittingcitations
- 2020Aluminium-poly(3,4-ethylenedioxythiophene) rechargeable battery with ionic liquid electrolytecitations
- 2019Relation between color and surface morphology of electrodeposited chromium for decorative applicationscitations
- 2019Fluidic self-assembly on electroplated multilayer solder bumps with tailored transformation imprinted melting pointscitations
- 2019Electrochemical deposition of silicon from a sulfolane-based electrolyte: effect of applied potentialcitations
- 2019Nanoscale morphological changes at lithium interface, triggered by the electrolyte composition and electrochemical cyclingcitations
- 2018Structure and formation of trivalent chromium conversion coatings containing cobalt on zinc plated steelcitations
- 2017An electrochemical quartz crystal microbalance study on electrodeposition of aluminum and aluminum-manganese alloyscitations
- 2016Ultrasound assisted electrodeposition of Zn and Zn-TiO2 coatingscitations
- 2012Electrochemical supercapacitors based on a novel graphene/conjugated polymer composite systemcitations
- 2010Do solvation layers of ionic liquids influence electrochemical reactions?citations
- 2009Novel amino-acid-based polymer/multi-walled carbon nanotube bio-nanocompositescitations
Places of action
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article
Do solvation layers of ionic liquids influence electrochemical reactions?
Abstract
<p>In this discussion paper we discuss our recent results on the electrodeposition of materials and in situ STM/AFM measurements which demonstrate that ionic liquids should not be regarded as neutral solvents which all have similar properties. In particular, we focus on differences in interfacial structure (solvation layers) on metal electrodes as a function of ionic liquid species. Recent theoretical and experimental results show that conventional double layers do not form on metal electrodes in ionic liquid systems. Rather, a multilayer architecture is present, with the number of layers determined by the ionic liquid species and the properties of the surface; up to seven discrete interfacial solvent layers are present on electrode surfaces, consequently there is no simple electrochemical double layer. Both the electrodeposition of aluminium and of tantalum are strongly influenced by ionic liquids: in 1-butyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)amide, [Py<sub>1,4</sub>]TFSA, aluminium is obtained as a nanomaterial, whereas in 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)amide, [EMIm]TFSA, a microcrystalline material is made. Tantalum can be deposited from [Py <sub>1,4</sub>]TFSA, whereas from [EMIm]TFSA only non-stoichiometric tantalum fluorides TaF<sub>x</sub> are obtained. It is likely that solvation layers influence these reactions.</p>