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Guerra, Gaetano
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Topics
Publications (10/10 displayed)
- 2024Cocrystalline Phases of Umbelliferone with Syndiotactic Polystyrene: A Route to Achieve Optical Brightening Filmscitations
- 2015Cure reaction of epoxy resins catalyzed by graphite-based nanofillercitations
- 2015Delamination of organically modified montmorillonite for reducing the filler networking with carbon black in poly(1,4-cis-isoprene) based nanocompositescitations
- 2014Delaminated and intercalated organically modified montmorillonite in poly(1,4-cis-isoprene) matrix. Indications of counterintuitive dynamic-mechanical behaviorcitations
- 2014Catalytic Activity of Graphite-Based Nanofillers on Cure Reaction of Epoxy Resinscitations
- 2012Monolithic nanoporous-crystalline aerogels based on PPOcitations
- 2011Nanoporous crystalline phases of poly(2,6-dimethyl-1,4-phenylene)oxidecitations
- 2011Aerogels and polymorphism of isotactic poly(4-methyl-pentene-1)citations
- 2010Hydrogen adsorption by δ and ε crystalline phases of syndiotactic polystyrene aerogelscitations
- 2010Storage of hydrogen as a guest of a nanoporous polymeric crystalline phasecitations
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article
Storage of hydrogen as a guest of a nanoporous polymeric crystalline phase
Abstract
A mechanism of H2 uptake, based on adsorption in the ordered cavities of nanoporous polymeric crystalline phases rather than on disordered amorphous polymeric surfaces, has been clearly established, for aerogels of syndiotactic polystyrene (s-PS) exhibiting the nanoporous d phase. An ordered arrangement of the H2 molecules is proven by FTIR spectra while the inclusion of H2 is assessed by gravimetric measurements and molecular simulations.