| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Brechin, Euan K.
University of Edinburgh
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (21/21 displayed)
- 2025Robust Y and Lu TrenSal catalysts for ring-opening polymerisation
- 2021Oxidation state variation in bis-calix[4]arene supported decametallic Mn clusterscitations
- 2020With complements of the ligands: an unusual S-shaped [Mn7]2 assembly from tethered calixarenescitations
- 2020Putting the squeeze on molecule-based magnets: exploiting pressure to develop magneto-structural correlations in paramagnetic coordination compoundscitations
- 2019Effect of pi-aromatic spacers on the magnetic properties and slow relaxation of double stranded metallacyclophanes with a Ln(III)-M-II-M-II-Ln(III) (Ln(III) = Gd-III, Dy-III, Y-III; M-II = Ni-II, Co-II) linear topologycitations
- 2019Molecular multifunctionality preservation upon surface deposition for a chiral single-molecule magnetcitations
- 2018Order in disorder:solution and solid-state studies of [MM] wheels (M = Cr, Al; M = Ni, Zn)citations
- 2018Order in disorder: solution and solid-state studies of [MIII 2 MII 5] wheels (MIII = Cr, Al; MII = Ni, Zn)citations
- 2018Order in disordercitations
- 2010MCD spectroscopy of hexanuclear Mn(III) salicylaldoxime single-molecule magnetscitations
- 2010Pressure-Induced Jahn-Teller Switching in a Mn12 nanomagnetcitations
- 2010High pressure studies of hydroxo-bridged Cu(II) dimerscitations
- 2010The effect of pressure on the crystal structure of [Gd(PhCOO) 3(DMF)]n to 3.7 GPa and the transition to a second phase at 5.0 GPacitations
- 2010The effect of pressure on the crystal structure of [Gd(PhCOO)(3)(DMF)](n) to 3.7 GPa and the transition to a second phase at 5.0 GPacitations
- 2009High pressure induced spin changes and magneto-structural correlations in hexametallic SMMscitations
- 2008Grafting derivatives of Mn-6 single-molecule magnets with high anisotropy energy barrier on Au(111) surfacecitations
- 2005Magnetic and theoretical characterization of a ferromagnetic Mn(III) dimercitations
- 2005Studies of an enneanuclear manganese single-molecule magnetcitations
- 2004Synthesis, structure, and magnetic properties of a [Mn22] wheel-like single-molecule magnetcitations
- 2004New routes to polymetallic clusters: Fluoride-based tri-, deca-, and hexaicosametallic MnIII clusters and their magnetic propertiescitations
- 2004New routes to polymetallic clusterscitations
Places of action
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article
High pressure studies of hydroxo-bridged Cu(II) dimers
Abstract
A combination of high pressure single crystal X-ray diffraction and high pressure SQUID magnetometry has been used to study three hydroxo-bridged copper(ii) dimers. [Cu2(OH)2(H2O) 2 (tmen)2](ClO4)2 (1; tmen = tetramethylethylenediamine), [Cu2(OH)2(tben)2] (ClO4)2 (2; tben = di-tbutylethylenediamine) and [Cu2(OH)2(bpy)2](BF4) 2 (3; bpy = 2,2′-bipyridine) have been structurally determined to 2.5, 0.9 and 4.7 GPa, respectively. The application of hydrostatic pressure imposes significant distortions and modifications in the structures of all three complexes. This is particularly true of the bond distances and angles between the metal centres and the bridging hydroxo groups. Compound 1 undergoes a phase transition between 1.2 and 2.5 GPa caused by the loss of a coordinated water molecule. This leads to a loss of symmetry and dramatic changes in the molecular structure of the complex. The structural changes are manifested in changes in the magnetic behaviour of the complexes as seen in dc susceptibility measurements up to ∼0.9 GPa for 1, 2 and 3: the exchange becomes less antiferromagnetic in 1 and 2 and more ferromagnetic in 3. © The Royal Society of Chemistry 2010.