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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Bras, Wim
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (15/15 displayed)
- 2021Data Mining of Polymer Phase Transitions upon Temperature Changes by Small and Wide-Angle X-ray Scattering Combined with Raman Spectroscopycitations
- 2021Data Mining of Polymer Phase Transitions upon Temperature Changes by Small and Wide-Angle X-ray Scattering Combined with Raman Spectroscopycitations
- 2019Monitoring morphology evolution within block copolymer microparticles during dispersion polymerisation in supercritical carbon dioxidecitations
- 2016Confocal depth-resolved micro-X-ray absorption spectroscopy study of chemically strengthened boroaluminosilicate glassescitations
- 2016Atomic layer deposition route to tailor nanoalloys of noble and non-noble metalscitations
- 2015XAS and XES techniques shed light on the dark side of Ziegler-Natta catalysts: Active-site generationcitations
- 2015XAS and XES Techniques Shed Light on the Dark Side of Ziegler–Natta Catalysts: Active‐Site Generationcitations
- 2015Small Angle X-ray Scattering Insights into the Architecture-Dependent Emulsifying Properties of Amphiphilic Copolymers in Supercritical Carbon Dioxidecitations
- 2014Influence of metal-support interaction on the surface structure of gold nanoclusters deposited on native SiO(x)/Si substratescitations
- 2014Synchrotron based in situ characterization during atomic layer deposition
- 2014A high pressure cell for supercritical CO2 on-line chemical reactions studied with x-ray techniquescitations
- 2010Quantifying hydrogel response using laser light scatteringcitations
- 2008Self-assembled poly(4-vinylpyridine) - Surfactant systems using alkyl and alkoxy phenylazophenolscitations
- 2007Autonomous Volume Transitions of a Polybase Triblock Copolymer Gel in a Chemically Driven pH-Oscillator
- 2003Are metastable, precrystallisation, density-fluctuations a universal phenomena?citations
Places of action
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article
Quantifying hydrogel response using laser light scattering
Abstract
The pH and counter-ion response of a microphase separated poly(methyl methacrylate)-block-poly(2-(diethylamino)ethyl methacrylate)-block-poly(methyl methacrylate) hydrogel has been investigated using laser light scattering on an imprinted micron scale topography. A quartz diffraction grating was used to create a micron-sized periodic structure on the surface of a thin film of the polymer and the resulting diffraction pattern used to calculate the swelling ratio of the polymer film in situ. A potentiometric titration and a sequence of counter ion species, taken from the Hofmeister series, have been used to compare the results obtained using this novel technique against small angle X-ray scattering (nanoscopic) and gravimetric studies of bulk gel pieces (macroscopic). For the first time, the technique has been proven to be an inexpensive and effective analytical tool for measuring hydrogel response on the microscopic scale.