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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Ikkala, Olli
Aalto University
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (33/33 displayed)
- 2024Respiratory rate monitoring with cellulose optical fiber
- 2021Cellulose optical fiber
- 2021Cellulose optical fiber
- 2021Electroferrofluids with nonequilibrium voltage-controlled magnetism, diffuse interfaces, and patternscitations
- 2020Methyl cellulose/cellulose nanocrystal nanocomposite fibers with high ductilitycitations
- 2019Effects of Chloride Concentration on the Water Disinfection Performance of Silver Containing Nanocellulose-based Compositescitations
- 2018Thermal Isomerization of Hydroxyazobenzenes as a Platform for Vapor Sensingcitations
- 2018Thermal Isomerization of Hydroxyazobenzenes as a Platform for Vapor Sensingcitations
- 2018Imaging Inelastic Fracture Processes in Biomimetic Nanocomposites and Nacre by Laser Speckle for Better Toughnesscitations
- 2017Toughness and Fracture Properties in Nacre-Mimetic Clay/Polymer Nanocompositescitations
- 2015Self-assembly of a functional oligo(aniline)-based amphiphile into helical conductive nanowirescitations
- 2015Water-Resistant, Transparent Hybrid Nanopaper by Physical Cross-Linking with Chitosancitations
- 2015Modular Architecture of Protein Binding Units for Designing Properties of Cellulose Nanomaterialscitations
- 2015Enhanced plastic deformations of nanofibrillated cellulose film by adsorbed moisture and protein-mediated interactionscitations
- 2015Hybrid supramolecular and colloidal hydrogels that bridge multiple length scales.
- 2013Photoinduced surface patterning of azobenzene-containing supramolecular dendrons, dendrimers and dendronized polymerscitations
- 2012Facile method for stiff, tough, and strong nanocomposites by direct exfoliation of multilayered graphene into native nanocellulose matrixcitations
- 2010Large-area, lightweight and thick biomimetic composites with superior material properties via fast, economic, and green pathwayscitations
- 2009Solid state nanofibers based on self-assembliescitations
- 2009Solid state nanofibers based on self-assemblies:from cleaving from self-assemblies to multilevel hierarchical constructscitations
- 2008Tuning the electrical switching of polymer/fullerene nanocomposite thin film devices by control of morphologycitations
- 2008Direct Imaging of Nanoscopic Plastic Deformation below Bulk Tg and Chain Stretching in Temperature-Responsive Block Copolymer Hydrogels by Cryo-TEMcitations
- 2008Evidence of PPII-like helical conformation and glass transition in a self-assembled solid-state polypeptide-surfactant complexcitations
- 2008Organic memory using [6,6]-phenyl-C 61 butyric acid methyl ester:Morphology, thickness and concentration dependence studiescitations
- 2008Self-assembled poly(4-vinylpyridine) - Surfactant systems using alkyl and alkoxy phenylazophenolscitations
- 2007Hierarchical porosity in self-assemhled polymerscitations
- 2007Hollow inorganic nanospheres and nanotubes with tunable wall thicknesses by atomic layer deposition on self-assembled polymeric templatescitations
- 2007Hollow inorganic nanospheres and nanotubes with tunable wall thicknesses by atomic layer deposition on self-assembled polymeric templatescitations
- 2007Metallic nanoparticles in a polymeric matrix
- 2007Metallic nanoparticles in a polymeric matrix:Electrical impedance switching and negative differential resistance
- 2007Phase behavior and temperature-responsive molecular filters based on self-assembly of polystyrene-block-poly(N-isopropylacrylamide)-block-polystyrenecitations
- 2007Hierarchical porosity in self-assemhled polymers:Post-modification of block copolymer-phenolic resin complexes hy pyrolysis allows the control of micro- and mesoporositycitations
- 2001Self-organization of nitrogen-containing polymeric supramolecules in thin filmscitations
Places of action
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article
Solid state nanofibers based on self-assemblies
Abstract
"Self-assemblies and their hierarchies are useful to construct soft materials with structures at different length scales and to tune the materials properties for various functions. Here we address routes for solid nanofibers based on different forms of self-assemblies. On the other hand, we discuss rational ""bottom-up'' routes for multi-level hierarchical self-assembled constructs, with the aim of learning more about design principles for competing interactions and packing frustrations. Here we use the triblock copolypeptide poly(L-lysine)-b-poly(gamma-benzyl-L-glutamate)-b-poly(L-lysine) complexed with 2'-deoxyguanosine 5'-monophosphate. Supramolecular disks (G-quartets) stabilized by metal cations are formed and their columnar assembly leads to a packing frustration with the cylindrical packing of helical poly(gamma-benzyl-L-glutamate), which we suggest is important in controlling the lateral dimensions of the nanofibers. We foresee routes for functionalities by selecting different metal cations within the G-quartets. On the other hand, we discuss nanofibers that are cleaved from bulk self-assemblies in a ""top-down'' manner. After a short introduction based on cleaving nanofibers from diblock copolymeric self-assemblies, we focus on native cellulose nanofibers, as cleaved from plant cell wall fibers, which are expected to have feasible mechanical properties and to be templates for functional nanomaterials. Long nanofibers with 5-20 nm lateral dimensions can be cleaved within an aqueous medium to allow hydrogels and water can be removed to allow highly porous, lightweight, and flexible aerogels. We further describe inorganic/organic hybrids as prepared by chemical vapour deposition and atomic layer deposition of the different nanofibers. We foresee functional materials by selecting inorganic coatings. Finally we briefly discuss how the organic template can be removed e. g., by thermal treatments to allow completely inorganic hollow nanofibrillar structures."