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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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White, Allan
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (54/54 displayed)
- 2011Structural and Infrared Spectroscopic Studies of Some Adducts of Divalent Metal Dihalides (MX2, M = Zn, Cd; X = CI, Br, I) with Variously Hindered Monodentate Nitrogen (Pyridine) Base Ligands (L = Pyridine, 2-Methylpyridine, and Quinoline) of 1:2 Stoichiometrycitations
- 2011Highly fluorous complexes of nickel, palladium and platinum: solubility and catalysis in high pressure CO2citations
- 2011Synthesis, spectroscopic and structural characterization of some novel adducts of copper(II) salts with unidentate nitrogen basescitations
- 2011Mechanochemical synthesis in copper(II) halide/pyridine systems: single crystal X-ray diffraction and IR spectroscopic studiescitations
- 2011Inhibition of metal ion complexation by an N2O2-donor macrocycle by incorporation of an intramolecularly hydrogen-bonding pendant phenolic groupcitations
- 2010Syntheses and molecular structures of some tricobalt carbonyl clusters containing 2,4,6-trimethyl-1,3,5-trithianecitations
- 2009Silver(I) methanesulfonate complexes containing diphosphine ligands: Spectroscopic and structural characterizationcitations
- 20091 : 1 complexes of silver(I) thiocyanate with (substituted) thiourea ligandscitations
- 2009Structural and spectroscopic studies of some adducts of silver(I) salts with ethylenethioureacitations
- 2008Structural forms in complexes of 2,9-dimenthyl-1,10-phenanthroline with simple salts of copper(I) and other univalent 'closed shell' speciescitations
- 2007Crystal Structures and EPR Spectra of Cu2+-Doped Magnesium(II) and Cadmium(II) Methoxyacetatescitations
- 2007Structural and Spectroscopic Studies of Halocuprate(I) and Haloargentate(I) Complexes [M2XnX′4−n]2−citations
- 2007A Linear Ru-Tl-Ru Complex Obtained from Halide Abstraction : An Example of Metal-Dative Bondingcitations
- 2007Cages on Surfaces : Thiol Functionalisation of CoIII Sarcophagine Complexescitations
- 2007Structural versatility in hydrated rare earth(III) 1,2-benzenedisulfonatescitations
- 2007Syntheses, structures and redox properties of some complexes containing the Os(dppe)Cp* fragment, including [{Os(dppe)Cp*}2(μ-C=CC=C)]citations
- 2007Synthesis, spectroscopic and structural characterization of the reaction products of quaternary cationic 2,2'-bipyridylium ligand bromide salts with metal halidescitations
- 2006Structural Consequences of S → Se Substitution in some Symmetrical [M(S2CNR2)3] Complexescitations
- 2006Polymetallation of alkenes: Formation of some complexes containing branched chain carbon-rich ligandscitations
- 2006Syntheses and Structures of Lithium and Sodium Salt Complexes with Alkylpolyamine Ligandscitations
- 2006The Structural Systematics of Protonation of Some Important Nitrogen-base Lgands. III Some (Univalent) Anion Salts of some Hindered Unidentate Nitrogen Basescitations
- 2006The structural definition of adducts of stoichiometry MX : dpex (2 : 3)(∞), M = CuI, AgI, X = simple anion, dpex = Ph2E(CH2)xEPh2, E = P, Ascitations
- 2006Syntheses and structures of adducts of stoichiometry MX:dpex (2:1)(n), M = CuI, AgI, X = (pseudo-) halogen, dppx = Ph2E(CH2)xEPh2, E = P, Ascitations
- 2006Complexes of Group 1 Salts with N,N′-Aromatic Bidentate Ligands, of 1 : 3 Salt : Base Ratiocitations
- 2006Structural characterizations of some adducts of silver(I) nitrate and perchlorate with some cyclic di- (or tri-) ene organic ligandscitations
- 2006Structure and magnetic properties of polynuclear chloro- and hydroxo- bridged copper II complexes formed by a tetramacrocyclic derivative of 1,4,7-triazacyclononanecitations
- 2006The Structural Systematics of Protonation of Some Important Nitrogen-base Ligands. I Some Univalent Anion Salts of Doubly Protonated 2, 2′:6′, 2″-Terpyridylcitations
- 2006Complexes of Group 1 Salts with N,N'-Aromatic Bidentate Ligands, of (Oligo-/Poly-) Nuclear or Ionic 1:2 Salt Base Ratiocitations
- 2006Heavier alkali metal complexes of the bulky alkyl ligand 2-(bis(trimethylsilyl)methyl)-6-methylpyridine: Crystal structures of [{6-Me(2 Pyr)}(Me3Si)2CNa(pmdta)] and [{6-Me(2-Pyr)}(Me3Si)2CK]∞citations
- 2006Synthesis and Structure of Potassium 1-Benzylimidazole-2-carboxylate · 2/3Hydrate
- 2005The structural definition of adducts of stoichiometry AgX:dppf (1:1)(n), X = simple anion, dppf = bis(diphenylphosphino)ferrocenecitations
- 2005The structural definition of adducts of stoichiometry MX:dppx (1:1) M = CuI, AgI, X = simple anion, dppx=Ph2P(CH 2)xPPh2, x = 3-6citations
- 2005Structural studies of rare earth/transition metal complex ion systems as a basis for understanding their thermal decomposition to mixed oxidescitations
- 2005Imidazole derivatives of binuclear copper(II) and nickel(II) complexes incorporating bis(1,4,7-triazacyclononan-1-yl) ligandscitations
- 2005Structural characterization of 1:1 adducts of silver(I) (pseudo-) halides (AgX, X = NCO, Cl, Br, I) with Ph2E(CH2)EPh2 (E = P, As) (‘dp(p/a)m’) and 4:3 adducts of copper(I) halide (CuX, X = Cl, Br, I), containing trinuclear cations, of the form [X2Ag3(dppm)3]X and [X2Cu3(dppm)3](CuX2) and the novel neutral [(OCN)3Ag3(dpam)3]citations
- 2005Synthesis, structure and optical limiting properties of organoruthenium-chalcogenide clusterscitations
- 2005Syntheses, structures and vibrational spectroscopy of some unusual silver(I) (pseudo-) halide/unidentate nitrogen base polymerscitations
- 2005Syntheses and structures of some adducts of silver(I) oxyanion salts with some 2-N,O-donor-substituted pyridine basescitations
- 2005Syntheses, structures and vibrational spectroscopy of some 1:2 and 1:3 adducts of silver(I) oxyanion salts with pyridine and piperidine bases containing non-coordinating 2(,6)-substituentscitations
- 2004Cation solvation in the solid state - temperature-dependent crystal structures in some metal perchlorates solvated by dimethylsulfoxidecitations
- 2004The trans-[py2AlCl4]- ('py' = pyridine) Anion, Structurally Characterized in Two Pyridinium Saltscitations
- 2004Coordination Complexes of Tin(IV) Chloride with Unidentate Nitrogen Basescitations
- 2004Syntheses and spectroscopic and structural characterization of silver(I) complexes containing tris(isobutyl)phosphine and polyl(azol-1-yl)boratescitations
- 2004Gold derivatives of scorpionates: comparison with the other coinage metal poly(pyrazolyl)borate analoguescitations
- 2004Solvent roles in metal ion coordination: the NiCl2 O-solvates, NiCl2 · 4MeOH, NiCl2 · 2MeOH · 0.5dioxan and NiCl2 · 2H2O · 2dioxancitations
- 2004Reactions of lanthanoid metals with 3,5-diphenylpyrazole at elevated temperatures: synthesis and structures of both homoleptic, [Ln3(Ph2pz)9] (Ln = La, Nd), [Ln2(Ph2pz)6] (Ln = Er, Lu), and heteroleptic, [Ln(Ph2pz)3(Ph2pzH)2] (Ln = La, Nd, Gd, Tb, Er or Yb), pyrazolate complexes
- 2003New Macrocyclic Ligands. XVI. Synthesis of a Series of N-Benzylated Macrocycles Incorporating N4O2-Donor setscitations
- 2003Cerium acetylacetonates—new aspects, including the lamellar clathrate [Ce(acac)4]·10H2Ocitations
- 2003Crystal and Molecular Structures of Some Alkynyl-Group 9/Group 11 Complexes [M2m4(C2R)8(PPh3)2](M = Rh, Ir; m = Cu, Ag; R = Ph, Fc (Ir/Cu only))citations
- 2003Structural characterization of [Ru3Mo(μ3-η1-CC}(μ-CO)3(CO)2(η-C5H5)5]: a revisitationcitations
- 2002Synthesis, spectroscopic and structural characterization of Cu(II) derivatives of tris(pyrazol-1-yl)methanescitations
- 2002Silver derivatives of tris(pyrazol-1-yl)methanes. A silver(I) nitrate complex containing a tris(pyrazolyl)methane coordinated in a bridging modecitations
- 2002Redox-active conducting polymers incorporating ferrocenes. Preparation, characterization and bio-sensing properties of ferrocenylpropyl and -butyl polypyrrolescitations
- 2001Metal ion recognition. Interaction of new oxygen-nitrogen donor macrocycles with selected transition and post-transition metal ionscitations
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article
1 : 1 complexes of silver(I) thiocyanate with (substituted) thiourea ligands
Abstract
Syntheses and single crystal X-ray structural characterizations, together with infrared spectroscopic studies, are recorded for 1:1 adducts of silver(I) thiocyanate with thiourea (‘tu’) and N,N′-diethylthiourea (‘detu’≡ (EtNH)2CS). The two complexes display novel and different polymeric forms. That formed with tu is a double-stranded form, comprising a pair of Ag(μ-S-tu)Ag(μ-… strands linked by pairs of μ-SCN anions, the whole array having quasi-2 symmetry about the polymer axis. The detu adduct takes the ionic form [Ag(detu)2](∞|∞)[Ag(SCN)2](∞|∞), both cation and anion being one-dimensional polymers lying in parallel, and both of the form …Ag(μ-S-L)2Ag(μ-… (L = SCN or detu), disposed about crystallographic axes. Redeterminations of the structures of AgSCN:tu, etu (1:2) (‘etu’ = ethylenethiourea, (CH2NH)2CS)) with quasi-trigonal silver atom environments (the etu adduct the more closely so), are also recorded as a basis for an IR spectroscopic characterization of the [(NCS)Ag(S-xtu)2] array. A mechanochemical/infrared study of the AgSCN:etu (1:1) system showed that no 1:1 complex exists in this case, the product being a mixture of the 1:2 complex and a novel 1:0.5 complex. The latter complex was prepared both mechanochemically and from solution, and characterized by infrared spectroscopy. Diagnostic ligand and metal–ligand bands in the IR and far-IR spectra are assigned for all of the complexes studied and for AgSCN and are discussed in relation to the structures of the complexes. The double degeneracy of the δ(SCN) mode of the coordinated thiocyanate is lifted and the first overtone of this band at gains intensity in the IR in the 1:1 complexes, behaviour that is not observed for the terminal bonding mode that is present in the 1:2 complexes.