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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Coppel, Yannick
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (15/15 displayed)
- 2024Towards chitosan-amorphous calcium phosphate nanocomposite: Co-precipitation induced by spray dryingcitations
- 2024Spray-dried ternary bioactive glass microspheres: Direct and indirect structural effects of copper-doping on acellular degradation behaviorcitations
- 2024Synthesis of TiO2/SBA-15 Nanocomposites by Hydrolysis of Organometallic Ti Precursors for Photocatalytic NO Abatement
- 2023Effect of Oxygen Poisoning on the Bidirectional Hydrogen Electrocatalysis in TaS2 Nanosheetscitations
- 2023Effect of Oxygen Poisoning on the Bidirectional Hydrogen Electrocatalysis in TaS 2 Nanosheetscitations
- 2022Nano-Structuration of WO3 Nanoleaves by Localized Hydrolysis of an Organometallic Zn Precursor: Application to Photocatalytic NO2 Abatementcitations
- 2022Nano-Structuration of WO3 Nanoleaves by Localized Hydrolysis of an Organometallic Zn Precursor: Application to Photocatalytic NO2 Abatementcitations
- 2022Bioactive glass nanoparticles decorated with catechol-functionalized polyesters: towards macroporous nanocomposite scaffolds
- 2020Nanoscale Metal Phosphide Phase Segregation to Bi/P Core/Shell Structure. Reactivity as a Source of Elemental Phosphoruscitations
- 2020Nanoscale Metal Phosphide Phase Segregation to Bi/P Core/Shell Structure. Reactivity as a Source of Elemental Phosphoruscitations
- 2019Urea-assisted cooperative assembly of phosphorus dendrimer–zinc oxide hybrid nanostructurescitations
- 2018A novel method for the metallization of 3D silicon induced by metastable copper nanoparticlescitations
- 2017Stabilization of Colloidal Ti, Zr, and Hf Oxide Nanocrystals by Protonated Tri- n -octylphosphine Oxide (TOPO) and Its Decomposition Products
- 2008Tailored Control and Optimisation of the Number of Phosphonic Acid Termini on Phosphorus-Containing Dendrimers for the Ex-Vivo Activation of Human Monocytescitations
- 2008Organotin chemistry for the preparation of fullerene-rich nanostructurescitations
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article
Organotin chemistry for the preparation of fullerene-rich nanostructures
Abstract
Hexameric organostannoxane derivatives 3 and 4 have been prepared by treatment of 2-phenoxyacetic acid (1) and benzoic acid (2), respectively, with n-BuSn(O)OH. The drum-like structure of these compounds, made up of a prismatic Sn6O6 core, has been confirmed by 119Sn NMR spectroscopy and single-crystal X-ray diffraction analysis. The reaction conditions used for the preparation of 3 and 4 have been applied to dendritic branches with one, two or four methanofullerene subunits at the periphery and a carboxylic acid function at the focal point to produce fullerene-rich nanostructures with a stannoxane core in almost quantitative yields. These compounds have been characterized by 1H, 13C, and 119Sn NMR spectroscopy. Their electrochemical properties have been investigated by cyclic voltammetry. The central stannoxane cage has been shown not to affect the electrochemical properties of the assembled fullerenes. Indeed, each C60 moiety behaves independently, just like the parent fullerene compounds.