| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Alias, Yatimah
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (8/8 displayed)
- 2023SBA-15 Templated Mesoporous NiFe<sub>2</sub>O<sub>4</sub>/MXene Nanocomposite for Alkaline Hydrogen Evolution Reactioncitations
- 2016Flexible supercapacitor based on electrochemically synthesized pyrrole formyl pyrrole copolymer coated on carbon microfiberscitations
- 2015Electrodeposition of copper oxide/polypyrrole/reduced graphene oxide as a nonenzymatic glucose biosensorcitations
- 2015A novel non-enzymatic H2O2 sensor based on polypyrrole nanofibers–silver nanoparticles decorated reduced graphene oxide nano compositescitations
- 2015A novel method for fabricating Fe2+ ion selective sensor using polypyrrole and sodium dodecyl sulfate based on carbon screen-printed electrodecitations
- 2015One-step hydrothermal green synthesis of silver nanoparticle-carbon nanotube reduced-graphene oxide composite and its application as hydrogen peroxide sensorcitations
- 2015One-step preparation of silver-polyaniline nanotube composite for non-enzymatic hydrogen peroxide detectioncitations
- 2008Nanoporous materials based on heteroleptic bilayers built up from bisphosphonium, p-sulfonatocalix[4]arene ionscitations
Places of action
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article
Nanoporous materials based on heteroleptic bilayers built up from bisphosphonium, p-sulfonatocalix[4]arene ions
Abstract
Sulfonatocalix[4]arene, 1, and bisphosphonium cation, 2, form extensive self-assembled arrays in the presence of lanthanide metal cations, building up new materials based on both types of ions. Systematic studies using the combinatorial approach reproducibly yielded three novel structures based on these ions. Complexes 3-5, were prepared by varying the ratio of the components, organic and metal ions, in addition to varying the pH and ionic strength of the solutions. The structural motifs in these complexes were found to be lanthanide specific and the complexes were obtained from a 1 : 1 ratio of the organic ions in the presence of an excess of lanthanide metal cations at near neutral pH. Two structures based on bilayers, 3 and 4, are accessible, differing in the ratio of the organic components, 1 and 2, 7 : 6 and 1 : 2, respectively. Complexes 3 and 4 have a supersized bilayer with 3 featuring a 2D channel system associated with a scaffolding role of the bisphosphonium cation. The structural motif in complex 5 is devoid of bilayer arrangements, instead taking on a compact structure.