Materials Map

Discover the materials research landscape. Find experts, partners, networks.

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The Materials Map is an open tool for improving networking and interdisciplinary exchange within materials research. It enables cross-database search for cooperation and network partners and discovering of the research landscape.

The dashboard provides detailed information about the selected scientist, e.g. publications. The dashboard can be filtered and shows the relationship to co-authors in different diagrams. In addition, a link is provided to find contact information.

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The Materials Map is still under development. In its current state, it is only based on one single data source and, thus, incomplete and contains duplicates. We are working on incorporating new open data sources like ORCID to improve the quality and the timeliness of our data. We will update Materials Map as soon as possible and kindly ask for your patience.

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in Cooperation with on an Cooperation-Score of 37%

Topics

Publications (3/3 displayed)

  • 2021Bimetallic and multimetallic nanoparticles as nanozymes88citations
  • 2009Influence of inner transducer properties on EMF response and stability of solid-contact anion-selective membrane electrodes based on metalloporphyrin ionophores17citations
  • 2006CMP(O) tripodands: Synthesis, potentiometric studies and extractions43citations

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Ivanova, Polina
1 / 1 shared
Górski, Łukasz
1 / 7 shared
Matusevich, Alexey
1 / 1 shared
Wang, Lin
1 / 5 shared
Meyerhoff, Mark E.
1 / 3 shared
Malinowska, Elżbieta
2 / 14 shared
Reinoso-Garcia, M. M.
1 / 1 shared
Selucky, P.
1 / 1 shared
Gruttner, C.
1 / 1 shared
Verboom, W.
1 / 1 shared
Gruner, B.
1 / 1 shared
Reinhoudt, D. N.
1 / 4 shared
Baca, J.
1 / 1 shared
Hill, C.
1 / 5 shared
Jańczewski, Dominik
1 / 3 shared
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2009
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Co-Authors (by relevance)

  • Ivanova, Polina
  • Górski, Łukasz
  • Matusevich, Alexey
  • Wang, Lin
  • Meyerhoff, Mark E.
  • Malinowska, Elżbieta
  • Reinoso-Garcia, M. M.
  • Selucky, P.
  • Gruttner, C.
  • Verboom, W.
  • Gruner, B.
  • Reinhoudt, D. N.
  • Baca, J.
  • Hill, C.
  • Jańczewski, Dominik
OrganizationsLocationPeople

article

CMP(O) tripodands: Synthesis, potentiometric studies and extractions

  • Reinoso-Garcia, M. M.
  • Pietrzak, Mariusz
  • Selucky, P.
  • Gruttner, C.
  • Verboom, W.
  • Gruner, B.
  • Reinhoudt, D. N.
  • Baca, J.
  • Malinowska, Elżbieta
  • Hill, C.
  • Jańczewski, Dominik
Abstract

Ligand systems containing three carbamoylmethylphosphonate (CMP) or -phosphine oxide (CMPO) moieties attached to a tripodal platform have been synthesized for metal complexation and subsequent extraction from HNO3 solutions. The incorporation into ion selective electrodes (ISE) and picrate extractions with Na+, K+, Ag+, Ca2+, Cd2+, Hg2+, Pb2+, Cu2+, Eu3+ and Fe3+ shows that CMPO tripodand 3 is very selective for Eu3+ and forms a very stable complex (logML = 28.3). Liquid–liquid extractions performed with Eu3+ and Am3+ show reasonable extraction properties of the CMP(O) tripodands 3, 11 and 13 in 1,1,2,2-tetrachloroethane, while in 1-octanol for all tripodands studied the distribution coefficients are low. Upon addition of the synergistic agent hexabrominated cobalt bis(dicarbollide) anion (bromo-COSAN) the distribution coefficients for Am3+ and Eu3+ extraction increase considerably for CMP(O) tripodands 3 and 4. Covalently linked COSAN only enhances the extraction of Am3+ and Eu3+ at 0.001–0.01 M HNO3. The functionalization of dendrimer coated magnetic silica particles with CMP(O) tripodands led to very effective particles ( 31 and 32) for Am3+ and Eu3+ removal from 0.01 M HNO3 solutions

Topics
  • impedance spectroscopy
  • cobalt
  • functionalization
  • dendrimer
  • liquid–liquid extraction