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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ali, M. A. |
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Rančić, M. |
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Azevedo, Nuno Monteiro |
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Rodríguez, Laura I.
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article
Metallodendrimers containing both ruthenium (internal layer) and rhenium (external layer)
Abstract
<p>The reaction of [Re(bipy)(CO)<sub>3</sub>(C≡Cpy)] with two carbosilane dendrimers containing terminal (p-cymene)Ru(triflate)<sub>2</sub> units gives bimetallic dendrimers functionalised with (p-cymene)Ru(triflate) (pyC≡C)Re(bipy)(CO)<sub>3</sub> units. Dendrimers of this kind can be envisaged as formed by two metal layers: the internal, constituted by ruthenium atoms, and the external, by rhenium metals. The luminescent properties of these species are only attributed to the rhenium moieties.</p>