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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Wright, Adrian
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (10/10 displayed)
- 2011Biocompatibility of magnesium phosphate minerals and their stability under physiological conditionscitations
- 2011Structure and magnetic properties of the cubic oxide fluoride BaFeO2Fcitations
- 2009Influence of cooling rate on the structure and composition of NaxCoO2 (x similar to 0.65)citations
- 2009Fluorination of perovskite-related phases of composition SrFe1-xSnxO3-deltacitations
- 2006Crystal structure and magnetic properties of Ca₂MnAlO₅.₅, an n=3 brownmillerite phasecitations
- 2004Crystallographic and magnetic structures of Y₀.₈Sr₂.₂Mn₂GaO₈-ɗ : a new vacancy-ordered perovskite structurecitations
- 2003Synthesis and Characterisation of the Reduced Double-Layer Manganite Sr₃Mn₂O₆₊xcitations
- 2002Structures & Magnetic Ordering in the BrownMillerite Phases, Sr₂MnGaO₅ and Ca₂MnALO₅citations
- 2002Synthesis and characterisation of reduced single layer manganite Sr₂MnO₃.₅₊xcitations
- 2001Synthesis and structure of Sr₂MnGaO₅, a new layered manganese oxidecitations
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article
Structures & Magnetic Ordering in the BrownMillerite Phases, Sr₂MnGaO₅ and Ca₂MnALO₅
Abstract
The crystal and magnetic structures of the two related phases, Sr-2 MnGaO5 and Ca2MnAlO5 are reported. Rietveld analysis of neutron powder diffraction has revealed that both phases adopt the brownmillerite structure. Subtle differences in structure lead to the structure of Sr2 MnGaO5 being best described by the space group Icmm (a = 5.4888(2) Angstrom, b = 16.2256(6) Angstrom, c = 5.35450(2) Angstrom at 2 K) while that of Ca2MnAlO5 is best described by Ibm2 (a = 5.46258(9) Angstrom, b = 14.9532(3) Angstrom, c = 5.23135(8) Angstrom at 2 K). Low temperature neutron powder diffraction data show that both phases have a simple antiferromagnetic structure. However, magnetisation data suggest a more complex picture of the magnetic order within these phases.