| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Graham, Duncan
University of Strathclyde
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (9/9 displayed)
- 2016Elucidation of the bonding of a near infrared dye to hollow gold nanospherescitations
- 2010Introducing dip pen nanolithography as a tool for controlling stem cell behaviour: unlocking the potential of the next generation of smart materials in regenerative medicinecitations
- 2009Functionalized nanoparticles for nucleic acid sequence analysis using optical spectroscopiescitations
- 2008Multidentate macromolecules for functionalisation, passivation and labelling of metal nanoparticlescitations
- 2006A TEM and electron energy loss spectroscopy (EELS) investigation of active and inactive silver particles for surface enhanced resonance raman spectroscopy (SERRS)citations
- 2005Benzotriazole rhodamine B: effect of adsorption on surface-enhanced resonance Raman scatteringcitations
- 2003The crystal structures of three primary products from the selective reduction of 2,4,6-trinitrotoluenecitations
- 2003Squid-based nondestructive evaluation of carbon fiber reinforced polymercitations
- 2001Benzotriazole maleimide as a bifunctional reactant for SERScitations
Places of action
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article
Benzotriazole maleimide as a bifunctional reactant for SERS
Abstract
The synthesis of a benzotriazole maleimide is reported and its use as a bifunctional compound demonstrated. The triazole moiety of the compound complexes strongly with metals such as copper and silver and can be used to form monolayers on metal surfaces. The maleimide acts as a dienophile and reacts with dienes to produce cycloadducts. We report the selective reaction of the benzotriazole maleimide with seven different dienes to produce a range of cycloadducts. These cycloadducts were then adsorbed onto a metal surface via the triazole group. The presence on the metal surface was confirmed by surface enhanced Raman scattering, SERS. SERS is a vibrational spectroscopy and as such provides a fingerprint of each compound examined. The cycloadducts all gave different spectra that allowed identification of each diene that had cyclised. The dienes did not produce SERS on their own and had to be reacted with the bifunctional benzotriazole maleimide prior to examination. This provides an illustration of the use of bifunctional reactants specifically designed to produce SERS active products and also provides an example of an efficient derivatisation chemistry for copper and silver metal surfaces.