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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Portale, Giuseppe, A.
University of Groningen
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (57/57 displayed)
- 2024Quasi-2D Lead–Tin Perovskite Memory Devices Fabricated by Blade Coatingcitations
- 2024PbI2 Passivation of Three Dimensional PbS Quantum Dot Superlattices Toward Optoelectronic Metamaterialscitations
- 2023Effect of Dynamically Arrested Domains on the Phase Behavior, Linear Viscoelasticity and Microstructure of Hyaluronic Acid - Chitosan Complex Coacervatescitations
- 2023Tuning the energy transfer in Ruddlesden-Popper perovskites phases through isopropylammonium addition - towards efficient blue emitterscitations
- 2023Nickel Boride (NixB) Nanocrystalscitations
- 2023The human factorcitations
- 2023Addition of Ammonium Thiocyanate Alters the Microstructure and Energetic Landscape of 2D/3D Perovskite Films
- 2022Film formation mechanism uncovered in 2D/3D mixed-dimensional lead halide perovskitescitations
- 2022Confined crystallization and polymorphism in iPP thin filmscitations
- 2022Two-Dimensional Triblock Peptide Assemblies for the Stabilization of Pickering Emulsions with pH Responsivenesscitations
- 2022Nanoscale Networks of Metal Oxides by Polymer Imprinting and Templating for Future Adaptable Electronicscitations
- 2022Crystallization kinetics of melt-mixed 3D hierarchical graphene/ polypropylene nanocomposites at processing-relevant cooling ratescitations
- 2022Taking a closer look - how the microstructure of Dion-Jacobson perovskites governs their photophysics
- 2022Taking a closer look - how the microstructure of Dion-Jacobson perovskites governs their photophysicscitations
- 2021Structural Transitions During Formation and Rehydration of Proton Conducting Polymeric Membranescitations
- 2021Amphipathic Side Chain of a Conjugated Polymer Optimizes Dopant Location toward Efficient N-Type Organic Thermoelectricscitations
- 2021Data Mining of Polymer Phase Transitions upon Temperature Changes by Small and Wide-Angle X-ray Scattering Combined with Raman Spectroscopycitations
- 2021Boosting the Thermoelectric Properties of PEDOTcitations
- 2021Crystallization driven boost in fill factor and stability in additive-free organic solar cellscitations
- 2021Molecular Doping Directed by a Neutral Radicalcitations
- 2021Proton conducting ABA triblock copolymers with sulfonated poly(phenylene sulfide sulfone) midblock obtained via copper-free thiol-click chemistry daggercitations
- 2021Revisiting the Mechanism of the Meso-to-α Transition of Isotactic Polypropylene and Ethylene-Propylene Random Copolymerscitations
- 2021Scalable, Template Driven Formation of Highly Crystalline Lead-Tin Halide Perovskite Filmscitations
- 2020Rapid Self-Assembly and Sequential Infiltration Synthesis of High χ Fluorine-Containing Block Copolymerscitations
- 2020Order-disorder transition in supramolecular polymer combs/brushes with polymeric side chainscitations
- 2020Electrical Conductivity of Doped Organic Semiconductors Limited by Carrier-Carrier Interactionscitations
- 2020Systematic Investigation on the Structure-Property Relationship in Isotactic Polypropylene Films Processed via Cast Film Extrusioncitations
- 2020Unraveling the Microstructure of Layered Metal Halide Perovskite Filmscitations
- 2020N-type organic thermoelectricscitations
- 2020Highly Stable Membranes of Poly(phenylene sulfide benzimidazole) Cross-Linked with Polyhedral Oligomeric Silsesquioxanes for High-Temperature Proton Transportcitations
- 2019Stable Cesium Formamidinium Lead Halide Perovskitescitations
- 2019Enhancing the crystallinity and perfecting the orientation of formamidinium tin iodide for highly efficient Sn-based perovskite solar cellscitations
- 2019Improved energy density and charge-discharge efficiency in solution processed highly defined ferroelectric block copolymer-based dielectric nanocompositescitations
- 2019Supramolecular Mimic for Bottlebrush Polymers in Bulkcitations
- 2019Favorable Mixing Thermodynamics in Ternary Polymer Blends for Realizing High Efficiency Plastic Solar Cellscitations
- 2019Chemical Solution Deposition of Ordered 2D Arrays of Room-Temperature Ferrimagnetic Cobalt Ferrite Nanodotscitations
- 2019A Photoaddressable Liquid Crystalline Phase Transition in Graphene Oxide Nanocompositescitations
- 2019Investigation of the Nanoscale Morphology in Industrially Relevant Clearcoats of Waterborne Polymer Colloids by Means of Variable-Angle-Grazing Incidence Small-Angle X-ray Scatteringcitations
- 2019Monitoring morphology evolution within block copolymer microparticles during dispersion polymerisation in supercritical carbon dioxidecitations
- 2018Operando SAXS/WAXS on the a-P/C as the Anode for Na-Ion Batteriescitations
- 2017Templated Sub-100-nm-Thick Double-Gyroid Structure from Si-Containing Block Copolymer Thin Filmscitations
- 2017On the Dimensional Control of 2D Hybrid Nanomaterialscitations
- 2017Sub-micrometer structure formation during spin coating revealed by time-resolved in situ laser and X-ray scatteringcitations
- 2017N-Type Organic Thermoelectricscitations
- 2016Structurally-driven Enhancement of Thermoelectric Properties within Poly(3,4-ethylenedioxythiophene) thin Filmscitations
- 2016Bundle Formation in Biomimetic Hydrogelscitations
- 2016Improving Stiffness, Strength, and Toughness of Poly(omega-pentadecalactone) Fibers through in Situ Reinforcement with a Vanillic Acid-Based Thermotropic Liquid Crystalline Polyestercitations
- 2016Tuning Ordered Pattern of Pd Species through Controlled Block Copolymer Self-Assemblycitations
- 2015About the Interactions Controlling Nafion's Viscoelastic Properties and Morphologycitations
- 2015Polymer Solar Cellscitations
- 2015In situ monitoring of laser-induced periodic surface structures formation on polymer films by grazing incidence small-angle X-ray scatteringcitations
- 2015Photoresponsive Nanoporous Smectic Liquid Crystalline Polymer Networkscitations
- 2015Unusual Melting Behavior in Flow Induced Crystallization of LLDPEcitations
- 2014Influence of metal-support interaction on the surface structure of gold nanoclusters deposited on native SiO(x)/Si substratescitations
- 2014Kinetics of the polymorphic transition in isotactic poly(1-butene) under uniaxial extension. New insights from designed mechanical historiescitations
- 2014A high pressure cell for supercritical CO2 on-line chemical reactions studied with x-ray techniquescitations
- 2007Small-angle energy-dispersive X-ray scattering using a laboratory-based diffractometer with a conventional sourcecitations
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article
Structurally-driven Enhancement of Thermoelectric Properties within Poly(3,4-ethylenedioxythiophene) thin Films
Abstract
International audience ; Due to the rising need for clean energy, thermoelectricity has raised as a potential alternative to reduce dependence on fossil fuels. Specifically, thermoelectric devices based on polymers could offer an efficient path for near-room temperature energy harvesters. Thus, control over thermoelectric properties of conducting polymers is crucial and, herein, the structural, electrical and thermoelectric properties of poly(3,4-ethylenedioxythiophene) (PEDOT) thin films doped with p-toluenesulfonate (Tos) molecules were investigated with regards to thin film processing. PEDOT:Tos thin films were prepared by in-situ polymerization of (3,4-ethylenedioxythiophene) monomers in presence of iron(III) p-toluenesulfonate with different co-solvents in order to tune the film structure. While the Seebeck coefficient remained constant, a large improvement in the electrical conductivity was observed for thin films processed with high boiling point additives. The increase of electrical conductivity was found to be solely in-plane mobility-driven. Probing the thin film structure by Grazing Incidence Wide Angle X-ray Scattering has shown that this behavior is dictated by the structural properties of the PEDOT:Tos films; specifically by the thin film crystallinity combined to the preferential edge-on orientation of the PEDOT crystallites. Consequentially enhancement of the power factor from 25 to 78.5 μW/mK 2 has been readily obtained for PEDOT:Tos thin films following this methodology.