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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Simons, Hugh
Technical University of Denmark
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (17/17 displayed)
- 2024Coupled local residual shear and compressive strain in NaNbO 3 ceramics under coolingcitations
- 2024Heterogeneous Antiferroelectric Ordering in NaNbO3-SrSnO3 Ceramics Revealed by Direct Superstructure Imaging
- 2024Heterogeneous Antiferroelectric Ordering in NaNbO 3 –SrSnO 3 Ceramics Revealed by Direct Superstructure Imaging
- 2024Coupled local residual shear and compressive strain in NaNbO3 ceramics under coolingcitations
- 2022Unveiling the Interaction Mechanisms of Electron and X-ray Radiation with Halide Perovskite Semiconductors using Scanning Nanoprobe Diffractioncitations
- 2022Unveiling the interaction mechanisms of electron and X-ray radiation with halide perovskite semiconductors using scanning nano-probe diffraction
- 2022Unveiling the interaction mechanisms of electron and X-ray radiation with halide perovskite semiconductors using scanning nano-probe diffraction
- 2021Bulk heterogeneity in barium titanate above the Curie temperaturecitations
- 2021Dislocation-toughened ceramicscitations
- 2020Thermal and electric field stability of square-net domain patterns in barium titanate
- 2020Effect of alloying BaTiO 3 with BiZn 1/2 Ti 1/2 O 3 on polarization reversalcitations
- 2019Sub-surface measurements of the austenite microstructure in response to martensitic phase transformationcitations
- 2018Dynamics and grain orientation dependence of the electric field induced phase transformation in Sm modified BiFeO 3 ceramicscitations
- 2017Ultra-low-angle boundary networks within recrystallizing grainscitations
- 2016Dual strain mechanisms in a lead-free morphotropic phase boundary ferroelectriccitations
- 2015Injection molded polymeric hard X-ray lensescitations
- 2013Tailoring the piezoelectric and relaxor properties of (Bi 1/2 Na 1/2 ) TiO 3 - BaTiO 3 via zirconium dopingcitations
Places of action
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article
Dual strain mechanisms in a lead-free morphotropic phase boundary ferroelectric
Abstract
Electromechanical properties such as d 33 and strain are significantly enhanced at morphotropic phase boundaries (MPBs) between two or more different crystal structures. Many actuators, sensors and MEMS devices are therefore systems with MPBs, usually between polar phases in lead (Pb)-based ferroelectric ceramics. In the search for Pb-free alternatives, systems with MPBs between polar and non-polar phases have recently been theorized as having great promise. While such an MPB was identified in rare-earth (RE) modified bismuth ferrite (BFO) thin films, synthesis challenges have prevented its realization in ceramics. Overcoming these, we demonstrate a comparable electromechanical response to Pb-based materials at the polar-to-non-polar MPB in Sm modified BFO. This arises from 'dual' strain mechanisms: ferroelectric/ferroelastic switching and a previously unreported electric-field induced transition of an anti-polar intermediate phase. We show that intermediate phases play an important role in the macroscopic strain response, and may have potential to enhance electromechanical properties at polar-to-non-polar MPBs.