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Kerr, Peter
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article
In situ single-crystal synchrotron X-ray diffraction studies of biologically active gases in metal-organic frameworks
Abstract
Metal-organic frameworks (MOFs) are well known for their ability toadsorb various gases. The use of MOFs for the storage and release ofbiologically active gases, particularly nitric oxide (NO) and carbonmonoxide (CO), has been a subject of interest. To elucidate the bindingmechanisms and geometry of these gases, an in situ single crystal X-raydiffraction (scXRD) study using synchrotron radiation at Diamond LightSource has been performed on a set of MOFs that display promising gasadsorption properties. NO and CO, were introduced into activatedNi-CPO-27 and the related Co-4,6-dihydroxyisophthalate (Co-4,6-dhip).Both MOFs show strong binding affinity towards CO and NO, however COsuffers more from competitive co-adsorption of water. Additionally, weshow that morphology can play an important role in the ease ofdehydration for these two systems.