• Askari, Mohammad Bagher
• Salarizadeh, Parisa
• Zadeh, Mohammad Hassan Ramezan

Abstract

<jats:title>Abstract</jats:title><jats:p>The potential of metal oxides in electrochemical energy storage encouraged our research team to synthesize molybdenum oxide/tungsten oxide nanocomposites (MoO<jats:sub>3</jats:sub>/WO<jats:sub>3</jats:sub>) and their hybrid with reduced graphene oxide (rGO), in the form of MoO<jats:sub>3</jats:sub>/WO<jats:sub>3</jats:sub>/rGO as a substrate with relatively good electrical conductivity and suitable electrochemical active surface. In this context, we presented the electrochemical behavior of these nanocomposites as an electrode for supercapacitors and as a catalyst in the oxidation process of methanol/ethanol. Our engineered samples were characterized by X-ray diffraction pattern and scanning electron microscopy. As a result, MoO<jats:sub>3</jats:sub>/WO<jats:sub>3</jats:sub> and MoO<jats:sub>3</jats:sub>/WO<jats:sub>3</jats:sub>/rGO indicated specific capacitances of 452 and 583 F/g and stability of 88.9% and 92.6% after 2000 consecutive GCD cycles, respectively. Also, MoO<jats:sub>3</jats:sub>/WO<jats:sub>3</jats:sub> and MoO<jats:sub>3</jats:sub>/WO<jats:sub>3</jats:sub>/rGO nanocatalysts showed oxidation current densities of 117 and 170 mA/cm<jats:sup>2</jats:sup> at scan rate of 50 mV/s, and stability of 71 and 89%, respectively in chronoamperometry analysis, in the MOR process. Interestingly, in the ethanol oxidation process, corresponding oxidation current densities of 42 and 106 mA/cm<jats:sup>2</jats:sup> and stability values of 70 and 82% were achieved. MoO<jats:sub>3</jats:sub>/WO<jats:sub>3</jats:sub> and MoO<jats:sub>3</jats:sub>/WO<jats:sub>3</jats:sub>/rGO can be attractive options paving the way for prospective alcohol-based fuel cells.</jats:p>

Topics

• nanocomposite
• surface
• molybdenum
• scanning electron microscopy
• x-ray diffraction
• tungsten
• electrical conductivity
• alcohol
• chronoamperometry