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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Petrov, R. H. | Madrid |
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| Azam, Siraj |
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| Ali, M. A. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Oh, Jin Young
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Publications (5/5 displayed)
- 2024Kinetically controlled metal-elastomer nanophases for environmentally resilient stretchable electronicscitations
- 2023Composite thin film nano/microstructure of solution-based metal oxide and UV-curable polymer for liquid crystal display
- 2022Alignment‐inducement property of physicochemically reconstructed EVA layer via plasma ion‐beam treatment for liquid crystal systemcitations
- 2021Uniformly aligned liquid crystal molecules on reformed poly(ethylene-co-vinyl acetate) layers driven by ion beam exposurecitations
- 2018Effect of Nonconjugated Spacers on Mechanical Properties of Semiconducting Polymers for Stretchable Transistorscitations
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article
Kinetically controlled metal-elastomer nanophases for environmentally resilient stretchable electronics
Abstract
Nanophase mixtures, leveraging the complementary strengths of each component, are vital for composites to overcome limitations posed by single elemental materials. Among these, metal-elastomer nanophases are particularly important, holding various practical applications for stretchable electronics. However, the methodology and understanding of nanophase mixing metals and elastomers are limited due to difficulties in blending caused by thermodynamic incompatibility. Here, we present a controlled method using kinetics to mix metal atoms with elastomeric chains on the nanoscale. We find that the chain migration flux and metal deposition rate are key factors, allowing the formation of reticular nanophases when kinetically in-phase. Moreover, we observe spontaneous structural evolution, resulting in gyrified structures akin to the human brain. The hybridized gyrified reticular nanophases exhibit strain-invariant metallic electrical conductivity up to 156% areal strain, unparalleled durability in organic solvents and aqueous environments with pH 2–13, and high mechanical robustness, a prerequisite for environmentally resilient devices.