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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Lazzaroni, Roberto
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (59/59 displayed)
- 2024Synergetic Hybridization Strategy to Enhance the Dynamicity of Poorly Dynamic CO2-derived Vitrimers achieved by a Simple Copolymerization Approachcitations
- 2024Single-Layered Imine-Linked Porphyrin-Based Two-Dimensional Covalent Organic Frameworks Targeting CO<sub>2</sub> Reductioncitations
- 2024A novel approach to design structural natural fiber composites from sustainable CO2-derived polyhydroxyurethane thermosets with outstanding properties and circular featurescitations
- 2023Exploring the effects of graphene and temperature in reducing electron beam damagecitations
- 2023Decoding Elasticity Build-Up and Network Topology in Free-Radical Cross-Linking Polymerization: A Combined Experimental and Atomistic Approachcitations
- 2023Integrating Benzoxazine-PDMS 3D Networks with Carbon Nanotubes for flexible Pressure Sensors.citations
- 2022Radical defects modulate the photocatalytic response in 2D-graphitic carbon nitride.citations
- 2022Nanoscale Electrical Investigation of Transparent Conductive Electrodes Based on Silver Nanowire Networkcitations
- 2022Nanoscale Electrical Investigation of Transparent Conductive Electrodes Based on Silver Nanowire Networkcitations
- 2022Robust and Direct Route for the Development of Elastomeric Benzoxazine Resins by Copolymerization with Aminescitations
- 2022Radical defects modulate the photocatalytic response in 2D-graphitic carbon nitridecitations
- 2021High Salt-Content Plasticized Flame-Retardant Polymer Electrolytescitations
- 2021Phosphonium-based polythiophene conjugated polyelectrolytes with different surfactant counterions: thermal properties, self-assembly and photovoltaic performancescitations
- 2020Elastic conducting polymer composites in thermoelectric modulescitations
- 2020Phosphonium‐based polythiophene conjugated polyelectrolytes with different surfactant counterions: thermal properties, self‐assembly and photovoltaic performancescitations
- 2020Phosphonium-based polythiopheneconjugated polyelectrolytes with differentsurfactant counterions: thermal properties,self-assembly and photovoltaic performancescitations
- 2020Phosphonium-based polythiophene conjugated polyelectrolytes with different surfactant counterions: thermal properties, self-assembly and photovoltaic performances
- 2019Hybrid interface in sepiolite rubber nanocomposites: Role of self-assembled nanostructure in controlling dissipative phenomenacitations
- 2019An innovative way for structuring plasma polymers at the nanoscale
- 2019Positive effect of functional side groups on the structure and properties of benzoxazine networks and nanocomposites
- 2016Elucidating Batch-to-Batch Variation Caused by Homocoupled Side Products in Solution-Processable Organic Solar Cellscitations
- 2016Elucidating Batch-to-Batch Variation Caused by Homocoupled Side Products in Solution-Processable Organic Solar Cellscitations
- 2016Expanding the light absorption of poly(3-hexylthiophene) by end-functionalization with pi-extended porphyrinscitations
- 2015Linear and propeller-like fluoro-isoindigo based donor–acceptor small molecules for organic solar cellscitations
- 2014Synthesis of TiO2-poly(3-hexylthiophene) Hybrid Particles through Surface-Initiated Kumada Catalyst-Transfer Polycondensationcitations
- 2014Semi-metallic polymerscitations
- 2014Semi-metallic polymerscitations
- 2013Azobenzene-based supramolecular polymers for processing MWCNTscitations
- 2012Synthesis and characterization of carboxystyryl end-functionalized poly(3-hexylthiophene) / TiO2 hybrids in view of photovoltaic applicationscitations
- 2011Nanostructured polymer blends: from core/shell nanoobjects to continuous three-phase morphologies
- 2011Large white organic light-emitting diode lighting panel on metal foilscitations
- 2010Poly(amino-methacrylate) as versatile agent for carbon nanotubes dispersion : an experimental, theoretical and application studycitations
- 2010Synthesis, characterization and comparative OFET behaviour of indenofluorene-bithiophene and terthiophene alternating copolymers
- 2010Deposition of Functional Organic Thin Films by Pulsed Plasma Polymerization: A Joint Theoretical and Experimental Characterizationcitations
- 2010Superhydrophobic aluminum surfaces by deposition of micelles of fluorinated block copolymerscitations
- 2010Synthesis and characterization of nanocomposites based on functional regioregular poly(3-hexylthiophene) and multiwall carbon nanotubescitations
- 2009Miscibility Between Differently-Shaped Mesogens: Structural and Morphological Study of a Phthalocyanine-Perylene Binary Systemcitations
- 2009Miscibility between differently shaped mesogens: Structural and morphological study of a phthalocyanine-perylene binary system.citations
- 2009On The Effect of Carbon Nanotubes on The Wettability and Surface Morphology of Hydrosilylation-Curing Silicone Coatings
- 2008CH-p interactions as the driving force for silicone-based nanocomposites with exceptional rheological and thermal propertiescitations
- 2008Poly(dimethylsiloxane)/carbon nanotubes nanocomposites: (nano)structured coatings for the control of marine biofouling
- 2008Microscopic Morphology of Blends Between a New 'All-acrylate' Radial Block Copolymer and a Rosin Ester Resin for Pressure Sensitive Adhesivescitations
- 2008Design and Use of Organic Nanoparticles Prepared from Star-Shaped Polymers with Reactive End Groupscitations
- 2008Fire and gas barrier properties of poly(styrene-co-acrylonitrile) nanocomposites using polycaprolactone/clay nanohybrid based-masterbatchcitations
- 2008Microscopic Morphology of Chlorinated Polyethylene-Based Nanocomposites Synthesized from Poly(e-caprolactone)/Clay Masterbatchescitations
- 2008Chlorinated Polyethylene Nanocomposites Using PCL/Clay Nanohybrid Masterbatchescitations
- 2008CH-π interactions as the driving force for silicone-based nanocomposites with exceptional propertiescitations
- 2007The influence of the matrix polarity on morphology and properties of ethylene vinyl acetate copolymer-carbon nanotube nanocompositescitations
- 2007Adhesive Properties of a Radial Acrylic Block Co-polymer with a Rosin Ester Resincitations
- 2006Polymer Layered Silicate/Carbon Nanotube Nanocomposites : The Catalyzed Polymerization Approachcitations
- 2006PLA-PMMA Blends: A Study by XPS and ToF-SIMScitations
- 2006Relationship between the Microscopic Morphology and the Charge Transport Properties in Poly(3-hexylthiophene) Field-Effect Transistorscitations
- 2005Molecular Dynamics Simulations of Nanocomposites Based on Poly(e-caprolactone) Grafted on Montmorillonite Claycitations
- 2004Electrodeposition of mixed adherent thin films of poly(ethyl acrylate) and polyacrylonitrile onto nickelcitations
- 2003Dynamic force microscopy analysis of nanocomposites, polymer blends, and block copolymers: Beyond imaging the surface morphology
- 2001Full-electrochemical preparation of conducting/insulating binary polymer filmscitations
- 2001Electrochemical strategies for the strengthening of polymer – metal interfaces
- 2000Microphase separation at the surface of block copolymers, as studied with atomic force microscopycitations
- 2000Synthesis, morphology, and mechanical properties of poly(methyl methacrylate)-b-poly(n-butyl acrylate)-b-poly (methyl methacrylate) triblocks. Ligated anionic polymerization vs atom transfer radical polymerizationcitations
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article
Semi-metallic polymers
Abstract
Polymers are lightweight, flexible, solution-processable materials that are promising for low-cost printed electronics as well as for mass-produced and large-area applications. Previous studies demonstrated that they can possess insulating, semiconducting or metallic properties; here we report that polymers can also be semi-metallic. Semi-metals, exemplified by bismuth, graphite and telluride alloys, have no energy bandgap and a very low density of states at the Fermi level. Furthermore, they typically have a higher Seebeck coefficient and lower thermal conductivities compared with metals, thus being suitable for thermoelectric applications. We measure the thermoelectric properties of various poly( 3,4-ethylenedioxythiophene) samples, and observe a marked increase in the Seebeck coefficient when the electrical conductivity is enhanced through molecular organization. This initiates the transition from a Fermi glass to a semi-metal. The high Seebeck value, the metallic conductivity at room temperature and the absence of unpaired electron spins makes polymer semi-metals attractive for thermoelectrics and spintronics.