| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Feist, Florian
Karlsruhe Institute of Technology
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (14/14 displayed)
- 2024Functionally Gradient Macroporous Polymers: Emulsion Templating Offers Control over Density, Pore Morphology, and Compositioncitations
- 2023Deconstructing 3D Structured Materials by Modern Ultramicrotomy for Multimodal Imaging and Volume Analysis across Length Scalescitations
- 2023Deconstructing 3D Structured Materials by Modern Ultramicrotomy for Multimodal Imaging and Volume Analysis across Length Scales
- 2023Laser printed microelectronicscitations
- 2023Direct Visualization of Homogeneous Chemical Distribution in Functional Polyradical Microspherescitations
- 2023Characterisation of thermally treated beech and birch by means of quasi-static tests and ultrasonic wavescitations
- 2021A Comparative Study on the Temperature Effect of Solid Birch Wood and Solid Beech Wood under Impact Loadingcitations
- 2021Zerstörungsfreie Charakterisierung von Furnieren für strukturelle Verbundwerkstoffe
- 2021Predicting strength of Finnish birch veneers based on three different failure criteriacitations
- 2020Temperature related properties of solid birch wood under quasi-static and dynamic bendingcitations
- 2019GVTR: A Generic Vehicle Test Rig Representative Of The Contemporary European Vehicle Fleet
- 2019Development Of A Certification Procedure For Numerical Pedestrian Models
- 2016Coding and decoding libraries of sequence-defined functional copolymers synthesized via photoligationcitations
- 2016Methodology for kinematic comparison of human body models for pedestrian simulations
Places of action
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article
Coding and decoding libraries of sequence-defined functional copolymers synthesized via photoligation
Abstract
Designing artificial macromolecules with absolute sequence order represents a considerable challenge. Here we report an advanced light-induced avenue to monodisperse sequence-defined functional linear macromolecules up to decamers via a unique photochemical approach. The versatility of the synthetic strategy-combining sequential and modular concepts-enables the synthesis of perfect macromolecules varying in chemical constitution and topology. Specific functions are placed at arbitrary positions along the chain via the successive addition of monomer units and blocks, leading to a library of functional homopolymers, alternating copolymers and block copolymers. The in-depth characterization of each sequence-defined chain confirms the precision nature of the macromolecules. Decoding of the functional information contained in the molecular structure is achieved via tandem mass spectrometry without recourse to their synthetic history, showing that the sequence information can be read. We submit that the presented photochemical strategy is a viable and advanced concept for coding individual monomer units along a macromolecular chain.