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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Zhang, Jing
King's College London
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (11/11 displayed)
- 2024A Scalable Microfluidic Platform for Nanoparticle Formulation:For Exploratory- and Industrial-Level Scalescitations
- 2023Evaluating the clinical validity of genes related to hemostasis and thrombosis using the ClinGen gene curation frameworkcitations
- 2021Conventional Glass-ionomer Cements: A Guide for Practitionerscitations
- 2021Investigation of electrical properties of peald-deposited Ti/Al<sub>2</sub>O<sub>3</sub>/Al/Si MIM capacitorscitations
- 2021Super-resolved optical mapping of reactive sulfur-vacancy in 2D transition metal dichalcogenidescitations
- 2019In vitro compressive strength and edge stability testing of directly repaired glass-ionomer cementscitations
- 2018In-vitro subsurface remineralisation of artificial enamel white spot lesions pre-treated with chitosan
- 2018Remineralisation of enamel white spot lesions pre-treated with chitosan in the presence of salivary pelliclecitations
- 2016Efficient hydrogen evolution in transition metal dichalcogenides via a simple one-step hydrazine reactioncitations
- 2009Complexity of shear localization in a Zr-based bulk metallic glasscitations
- 2007Structural and Morphological Characterization of Cerium Oxide Nanocrystals Prepared by Hydrothermal Synthesiscitations
Places of action
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article
Efficient hydrogen evolution in transition metal dichalcogenides via a simple one-step hydrazine reaction
Abstract
<jats:title>Abstract</jats:title><jats:p>Hydrogen evolution reaction is catalysed efficiently with precious metals, such as platinum; however, transition metal dichalcogenides have recently emerged as a promising class of materials for electrocatalysis, but these materials still have low activity and durability when compared with precious metals. Here we report a simple one-step scalable approach, where MoO<jats:sub>x</jats:sub>/MoS<jats:sub>2</jats:sub> core-shell nanowires and molybdenum disulfide sheets are exposed to dilute aqueous hydrazine at room temperature, which results in marked improvement in electrocatalytic performance. The nanowires exhibit ∼100 mV improvement in overpotential following exposure to dilute hydrazine, while also showing a 10-fold increase in current density and a significant change in Tafel slope. <jats:italic>In situ</jats:italic> electrical, gate-dependent measurements and spectroscopic investigations reveal that hydrazine acts as an electron dopant in molybdenum disulfide, increasing its conductivity, while also reducing the MoO<jats:sub>x</jats:sub> core in the core-shell nanowires, which leads to improved electrocatalytic performance.</jats:p>