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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Davidson, Patrick
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (13/13 displayed)
- 2024Influence of polymerisation parameters on the electro-optical properties of polymer-stabilised liquid crystals for smart glass applicationcitations
- 2024Multifunctional Supramolecular Gels with Strong Mechanical Properties Formed by Self-Assembly of Polyoxometalate-Based Coordination Polymers
- 2022Critical role of water on the synthesis and gelling of gamma-In2S3 nanoribbons with giant aspect ratio
- 2021Gold-clay nanocomposite colloids with liquid-crystalline and plasmonic properties
- 2018Comparison of single-ion-conductor block-copolymer electrolytes with Polystyrene- TFSI and Polymethacrylate- TFSI structural blockscitations
- 2018Optical and X-ray scattering studies of the electric field-induced orientational order in colloidal suspensions of pigment nanorodscitations
- 2018Swelling Inhibition of Liquid Crystalline Colloidal Montmorillonite and Beidellite Clays by DNAcitations
- 2016A liquid-crystalline hexagonal columnar phase in highly-dilute suspensions of imogolite nanotubescitations
- 2015Room-Temperature, Strain-Tunable Orientation of Magnetization in a Hybrid Ferromagnetic Co Nanorod-Liquid Crystalline Elastomer Nanocomposite
- 2014Hybrid Nanocomposites with Tunable Alignment of the Magnetic Nanorod Fillercitations
- 2013Electric-Field Alignment of Chitin Nanorod-Siloxane Oligomer Reactive Suspensionscitations
- 2012The interaction of charged nanoparticles at interfacescitations
- 2008Photochromic Hybrid Organic−Inorganic Liquid-Crystalline Materials Built from Nonionic Surfactants and Polyoxometalates: Elaboration and Structural Studycitations
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article
A liquid-crystalline hexagonal columnar phase in highly-dilute suspensions of imogolite nanotubes
Abstract
Liquid crystals have found wide applications in many fields ranging from detergents to information displays and they are also increasingly being used in the 'bottom-up' self-assembly approach of material nano-structuration. Moreover, liquid-crystalline organizations are frequently observed by biologists. Here we show that one of the four major lyotropic liquid-crystal phases, the columnar one, is much more stable on dilution than reported so far in literature. Indeed, aqueous suspensions of imogolite nanotubes, at low ionic strength, display the columnar liquid-crystal phase at volume fractions as low as B0.2%. Consequently, due to its low visco-elasticity, this columnar phase is easily aligned in an alternating current electric field, in contrast with usual columnar liquid-crystal phases. These findings should have important implications for the statistical physics of the suspensions of charged rods and could also be exploited in materials science to prepare ordered nanocomposites and in biophysics to better understand solutions of rod-like biopolymers.