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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Walker, David
University of Warwick
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (17/17 displayed)
- 2024Untangling free carrier and exciton dynamics in layered hybrid perovskites using ultrafast optical and terahertz spectroscopycitations
- 2023Untangling free carrier and exciton dynamics in layered hybrid perovskites using ultrafast optical and terahertz spectroscopycitations
- 2023Operando X-ray and Post-mortem Investigations of Electrochemical Degradation in Single-crystalline LiNi0.8Mn0.1Co0.1O2–Graphite pouch cellscitations
- 2023Tetragonal Kondo Insulator EuCd2Sb2 Discovered via High Pressure High Temperature Synthesiscitations
- 2023Quantifying electrochemical degradation in single-crystalline LiNi0.8Mn0.1Co0.1O2–graphite pouch cells through operando X-ray and post-mortem investigations
- 2023Data for Influence of co-reactants on surface passivation by nanoscale hafnium oxide layers grown by atomic layer deposition on siliconcitations
- 2023Hafnium oxide : a thin film dielectric with controllable etch resistance for semiconductor device fabricationcitations
- 2020Ambient and high pressure CuNiSb₂citations
- 2019Advanced steam measurement techniques: a study of how electrical capacitance measurements are affected by the spatial positioning of water within wet steam
- 2018MnFe0.5Ru0.5O3: An Above-Room-Temperature Antiferromagnetic Semiconductorcitations
- 2018Synthesizing bijective lensescitations
- 2018Cs1−xRbxSnI3 light harvesting semiconductors for perovskite photovoltaicscitations
- 2018Cs 1-: X Rb x SnI 3 light harvesting semiconductors for perovskite photovoltaicscitations
- 2015Thermal, compositional, and compressional demagnetization of cementitecitations
- 2015Structural, optical and vibrational properties of self-assembled Pbn+1(Ti1−xFex)nO3n+1−δ Ruddlesden-Popper superstructurescitations
- 2013Thin film LaYbO3 capacitive structures grown by pulsed laser depositioncitations
- 2001Synthesis and thermal decomposition of tetragonal RbClO4 and volume of fluid O2 from 2 to 9 GPacitations
Places of action
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article
Synthesis and thermal decomposition of tetragonal RbClO4 and volume of fluid O2 from 2 to 9 GPa
Abstract
<p>Orthorhombic (O) RbClO<sub>4</sub> transforms to a new tetragonal (T) form at pressures above 20 kbar. Thermal decomposition proceeds through the reversible equilibrium reaction T RbClO<sub>4</sub> = B2 RbCl + 2O<sub>2</sub> at modestly increasing temperatures centered ∼550°C over the pressure range investigated from 20 to 90 kbar. Cell volumes for T RbClO<sub>4</sub> and B2 RbCl were determined by high-pressure, high-temperature, in situ X-ray diffraction on station 16.4 of the Daresbury Synchrotron Radiation Source, from which the partial molar volume of O<sub>2</sub> along the decomposition curve was determined. This volume (∼10 cm<sup>3</sup>/mol) is in close agreement with volumes determined from studies of the thermal decomposition of KClO<sub>3</sub> and KClO<sub>4</sub> but is difficult to reconcile with fluid O<sub>2</sub> volumes determined using shock wave techniques. If these new O<sub>2</sub> partial molar volumes are relevant to molten iron solutions, then storage of substantial amounts of O<sub>2</sub> in the core becomes feasible.</p>