| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Mallet-Ladeira, Sonia
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (8/8 displayed)
- 2024Synthesis, characterization, and inhibition effects of a novel eugenol derivative bearing pyrrole functionalities on the corrosion of mild steel in a HCl acid solutioncitations
- 2023Acetylacetonate Ruthenium Nitrosyls: A Gateway to Nitric Oxide Release in Water Under Near-Infrared Excitation by Two-Photon Absorptioncitations
- 2021Superconducting super-organized nanoparticles of the superconductor (BEDT-TTF)2Cu(NCS)2citations
- 2021Superconducting super-organized nanoparticles of the superconductor (BEDT-TTF)2Cu(NCS)2citations
- 2018Designed single-source precursors for iron germanide nanoparticles: colloidal synthesis and magnetic propertiescitations
- 2017Replacing two chlorido ligands by a bipyridine ligand in ruthenium nitrosyl complexes with NO-release capabilities: A comparative studycitations
- 2016Does the sign of the Cu–Gd magnetic interaction depend on the number of atoms in the bridge?citations
- 2015Iron Complexes with Stabilized Germylenes: Syntheses and Characterizationscitations
Places of action
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article
Iron Complexes with Stabilized Germylenes: Syntheses and Characterizations
Abstract
The reactivity of amidinate (1a,b, 2a)- or NHC (5a,b)-stabilized germanium(II) compounds toward diiron nonacarbonyl has been investigated. These germylenes act as two-electron carbene-like ligands and lead to stable germylene iron complexes by exchange reaction of a carbonyl ligand. Whereas the amidinato chloro germylenes lead to stable complexes, a bis(iron germylene) oxide was obtained from the bis-amidinato germylene. The reactions of NHC-stabilized germylenes (5a,b) with Fe2(CO)9 were also explored, giving donor–acceptor complexes of germylenes. All the germanium–iron complexes were fully characterized (1H and 13C NMR and IR) including by single-crystal X-ray diffraction structure determinations.