Materials Map

Discover the materials research landscape. Find experts, partners, networks.

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The Materials Map is an open tool for improving networking and interdisciplinary exchange within materials research. It enables cross-database search for cooperation and network partners and discovering of the research landscape.

The dashboard provides detailed information about the selected scientist, e.g. publications. The dashboard can be filtered and shows the relationship to co-authors in different diagrams. In addition, a link is provided to find contact information.

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Materials Map under construction

The Materials Map is still under development. In its current state, it is only based on one single data source and, thus, incomplete and contains duplicates. We are working on incorporating new open data sources like ORCID to improve the quality and the timeliness of our data. We will update Materials Map as soon as possible and kindly ask for your patience.

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in Cooperation with on an Cooperation-Score of 37%

Topics

Publications (2/2 displayed)

  • 2004Asymmetric C-C bond formation with L-prolinol derived chiral catalysts immobilized on polymer fibers32citations
  • 2001Immobilization of chiral ligands on polymer fibers by electron beam induced grafting and applications in enantioselective catalysis30citations

Places of action

Chart of shared publication
Leino, Reko
2 / 6 shared
Degni, S.
2 / 2 shared
Chart of publication period
2004
2001

Co-Authors (by relevance)

  • Leino, Reko
  • Degni, S.
OrganizationsLocationPeople

article

Immobilization of chiral ligands on polymer fibers by electron beam induced grafting and applications in enantioselective catalysis

  • Leino, Reko
  • Degni, S.
  • Wilen, Ce
Abstract

Styrenic TADDOL and L-prolinol-derived monomers were immobilized on polyethylene fibers by electron beam induced preirradiation grafting using styrene as comonomer. The polymer-supported chiral ligands were utilized as catalysts in the asymmetric addition of diethylzinc to benzaldehyde. Fiber-bound titanium TADDOLate gave a quantitative conversion of benzaldehyde to 1-phenylpropan-1-ol in a 97:3 S/R enantiomeric ratio. The catalyst was successfully regenerated and employed in subsequent reactions with retention of high enantioselectivities.

Topics
  • polymer
  • titanium