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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Ludwigs, Sabine
University of Stuttgart
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (9/9 displayed)
- 2023Autonomous Adaption of Intelligent Humidity‐Programmed Hydrogel Patches for Tunable Stiffness and Drug Releasecitations
- 2020Hybrid spintronic materials from conducting polymers with molecular quantum bits
- 2019From Isotropic to Anisotropic Conductivities in P(NDI2OD-T2) by (Electro-)Chemical Doping Strategiescitations
- 2019Triphenylamine and some of its derivatives as versatile building blocks for organic electronic applicationscitations
- 2016Achieving 6.7% Efficiency in P3HT/Indene‐C70 Bisadduct Solar Cells through the Control of Vertical Volume Fraction Distribution and Optimized Regio‐Isomer Ratioscitations
- 2014High-Temperature Rubbing: A Versatile Method to Align π-Conjugated Polymers without Alignment Substratecitations
- 2011In situ electrochemical monitoring of selective etching in ordered mesoporous block-copolymer templatescitations
- 2010Soft-etch mesoporous hole-conducting block copolymer templatescitations
- 2010Control of gyroid forming block copolymer templatescitations
Places of action
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article
Soft-etch mesoporous hole-conducting block copolymer templates
Abstract
<p>We present a mesoporous hole-conducting polymer film resulting from spontaneous block copolymer self-assembly based on a simple spin-coating protocol. A diblock copolymer consisting of a triphenylamine side group polymer and a poly(D,L-lactide) block (PSTPA-b-PLA) is shown to microphase separate to form ordered 13 nm cylindrical PLA microdomains embedded in the semiconducting PSTPA matrix. Partially ordered and film-spanning PLA domains could be identified in films immediately after spin coating from toluene solutions on conducting substrates. Selective mild etching of the minority PLA domains (in weak aqueous base) leads to a mesoporous hole-conducting polymer matrix. The pore structure is replicated electrochemically in platinum, demonstrating the viability of this approach to producing nano-organized heterojunction structures in thin films.</p>