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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Cundy, Andy
University of Southampton
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (13/13 displayed)
- 2020Novel nanostructured iron oxide cryogels for arsenic (As(III)) removalcitations
- 2019A cryogel-based bioreactor for water treatment applicationscitations
- 2019Flexural performance of reinforced concrete beams strengthened with fibre reinforced geopolymer concrete under accelerated corrosioncitations
- 2018A novel corrosion resistant repair technique for existing reinforced concrete (RC) elements using polyvinyl alcohol fibre reinforced geopolymer concrete (PVAFRGC)citations
- 2017Steel fibre reinforced geopolymer concrete (SFRGC) with improved microstructure and enhanced fibre-matrix interfacial propertiescitations
- 2017Tensile properties of a novel fibre reinforced geopolymer composite with enhanced strain hardening characteristicscitations
- 2017Effect of undensified silica fume on the dispersion of carbon nanotubes within a cementitious compositecitations
- 2017Mechanical performance of novel cement-based composites prepared with nano-fibres, and hybrid nano- and micro-fibrescitations
- 2016Development of geopolymer mortar under ambient temperature for in situ applicationscitations
- 2014y-Al2O3-based nanocomposite adsorbents for arsenic(V) removal: Assessing performance, toxicity and particle leakagecitations
- 2012Driving forces of conformational changes in single-layer graphene oxidecitations
- 2011High efficiency removal of dissolved As(III) using iron nanoparticle-embedded macroporous polymer compositescitations
- 2005Electrokinetic iron pan generation in unconsolidated sediments: implications for contaminated land remediation and soil engineeringcitations
Places of action
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article
Driving forces of conformational changes in single-layer graphene oxide
Abstract
The extensive oxygen-group functionality of single-layer graphene oxide proffers useful anchor sites for chemical functionalization in the controlled formation of graphene architecture and composites. However, the physicochemical environment of graphene oxide and its single-atom thickness facilitate its ability to undergo conformational changes due to responses to its environment, whether pH, salinity, or temperature. Here, we report experimental and molecular simulations confirming the conformational changes of single-layer graphene oxide sheets from the wet or dry state. MD, PM6, and ab initio simulations of dry SLG and dry and wetted SLGO and electron microscopy imaging show marked differences in the properties of the materials that can explain variations in previously observed results for the pH dependent behavior of SLGO and electrical conductivity of chemically modified graphene-polymer composites. Understanding the physicochemical responses of graphene and graphene oxide architecture and performing selected chemistry will ultimately facilitate greater tunability of their performance.