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| Naji, M. |
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Sart, Gerrit Gobius Du
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Publications (3/3 displayed)
- 2013Synthesis and structural characterization of group 4 metal alkoxide complexes of N, N, N ′,N ′-tetrakis(2-hydroxyethyl)ethylenediamine and their use as initiators in the ring-opening polymerization (ROP) of rac -lactide under industrially relevant conditionscitations
- 2010Supramolecular Triblock Copolymer Complexes
- 2010Self-Assembly of Supramolecular Triblock Copolymer Complexescitations
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article
Self-Assembly of Supramolecular Triblock Copolymer Complexes
Abstract
<p>Four different poly(tert-butoxystyrene)-b-polystyrene-b-poly(4-vinylpyridine)(PtBOS-b-PS-b-P4VP) linear triblock copolymers, with the P4VP weight fraction varying from 0.08 to 0.39, were synthesized via sequential anionic polymerization. The values of the unknown interaction parameters between styrene and tert-butoxystyrene and between tert-butoxystyrene and 4-vinylpyridine were determined from random copolymer blend miscibility studies and found to satisfy 0.031 <chi(S.tBOS) <0.034 and 0.39 <chi(4VP.tBOS)</p>