693.932 PEOPLE
| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Ameduri, Bruno
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (105/105 displayed)
- 2024Tailoring Electroactive β- and γ-Phases via Synthesis in the Nascent Poly(vinylidene fluoride) Homopolymerscitations
- 2024Hydroxide-ion induced complete mineralization of poly(tetrafluoroethylene-co-hexafluoropropylene) copolymer (FEP) in subcritical watercitations
- 2023Synthesis and Characterization of Core–Double-Shell-Structured PVDF-grafted-BaTiO3/P(VDF-co-HFP) Nanocomposite Filmscitations
- 2023Synthesis and Characterization of Core-Double-Shell-Structured PVDF-grafted BaTiO3/P(VDF-co-HFP) Nanocomposite Filmscitations
- 2023One-Step Multifunctionalization of Flax Fabrics for Simultaneous Flame-Retardant and Hydro-Oleophobic Properties Using Radiation-Induced Graft Polymerizationcitations
- 2023Original Fluorinated Non-Isocyanate Polyhydroxyurethanescitations
- 2023Efficient fluoride recovery from poly(vinylidene fluoride), poly(vinylidene fluoride-co-hexafluoropropylene) copolymer and poly(ethylene-co-tetrafluoroethylene) copolymer using superheated water with alkaline reagentcitations
- 2022Flame retardancy of flax fibers by pre-irradiation grafting of a phosphonate monomercitations
- 2022Growth-Induced Wrinkles and Dotlike Patterns of a Swollen Fluoroalkylated Thin Film by the Reaction of Surface-Attached Polymethylhydrosiloxanecitations
- 2021Novel single-ion conducting electrolytes based on polyvinylidene fluoride polymer for Lithium metal batteriescitations
- 2021Vinylidene fluoride polymerization by metal-free selective activation of hydrogen peroxide: microstructure determination and mechanistic studycitations
- 2021Radio-grafting of phosphorus flame retardant on flax fabrics: Pre-irradiation method
- 2021Well-defined Fluorinated Copolymers: Current Status and Future Perspectivescitations
- 2021Does the Oxa-Michael Reaction of 2-Trifluoromethacrylic Acid Lead to Original Fluorinated Polyester?citations
- 2021May the Oxa-Michael Reaction of 2-Trifluoromethacrylic Acid Lead to Original Fluorinated Polyester?citations
- 2021Modification of Flax Fabrics by Pre-Irradiation Graftings of Phosphorus-Based Flame Retardants
- 2020New fluorinated polymer- based nanocomposites via combination of sol -gel chemistry and reactive extrusion for polymer electrolyte membranes fuel cells (PEMFCs)citations
- 2020Fluoroalkyl Pentacarbonylmanganese(I) Complexes as Initiators for the Radical (co)Polymerization of Fluoromonomerscitations
- 2020Poly(vinylidene fluoride)-based Complex Macromolecular Architectures: From Synthesis to Properties and Applicationscitations
- 2020Molecular Aggregation Structure and Surface Properties of Biomimetic Catechol-Bearing Poly[2-(perfluorooctyl)ethyl acrylate] and Its Application to Superamphiphobic Coatingscitations
- 2020Recent progress on core-shell structured BaTiO3@polymer/fluorinated polymers nanocomposites for high energy storage: Synthesis, dielectric properties and applicationscitations
- 2020Evaluation of core–shell poly(vinylidene fluoride)-grafted-Barium titanate (PVDF-g-BaTiO3) nanocomposites as a cathode binder in batteriescitations
- 2020The Promising Future of Fluoropolymerscitations
- 2019Preparation and dielectric properties of poly(acrylonitrile- co -2,2,2-trifluoroethyl methacrylate) materials via radical emulsion copolymerizationcitations
- 2018Syntheses of 2-(trifluoromethyl)acrylate-containing block copolymers via RAFT polymerization using a universal chain transfer agentcitations
- 2018Synthesis and characterization of new fluorinated copolymers based on azole groups for fuel cell membranescitations
- 2018Outstanding telechelic perfluoropolyalkylethers and applications therefromcitations
- 2017Poly(fluoroacrylate)s with tunable surface hydrophobicity via radical copolymerization of 2,2,2-trifluoroethyl α-fluoroacrylate and 2-(trifluoromethyl)acrylic acidcitations
- 2017Poly(fluoroacrylate)s with tunable surface hydrophobicity via radical copolymerization of 2,2,2-trifluoroethyl α-fluoroacrylate and2-(trifluoromethyl)acrylic acidcitations
- 2017Deeper Insight Into the RDRP Polymerization of Vinylidene Fluoride
- 2017Photocrosslinked PVDF-based star polymer coatings: an all-in-one alternative to PVDF/PMMA blends for outdoor applicationscitations
- 2017Vinylidene Fluoride-Based Polymer Network via Cross-Linking of Pendant Triethoxysilane Functionality for Potential Applications in Coatingscitations
- 2017Bringing Fluorine in Nanomaterials
- 2017Poly(vinylidene fluoride) Containing Phosphonic Acid as Anticorrosion Coating for Steelcitations
- 2016Semi-interpenetrating polymer networks by cationic photopolymerization: Fluorinated vinyl ether chains in a hydrogenated vinyl ether networkcitations
- 2016Kinetics and Mechanistic Aspects of the Iodine Transfer Copolymerization of Vinylidene Fluoride with 2,3,3,3-Tetrafluoro-1-propene and Functionalization into w-Hydroxy Fluorinated Copolymercitations
- 2016Nitroxide-Mediated Alternating Copolymerization of Vinyl Acetate with tert-Butyl-2-trifluoromethacrylate Using a SG1-Based Alkoxyaminecitations
- 2015Synthesis of aliphatic polyamide bearing fluorinated groupsfrom e-caprolactam and modified cyclic lysinecitations
- 2015A new oligo(hexafluoropropylene oxide)-b-oligo-(ethylene oxide) diblock surfactant obtained by radical reactionscitations
- 2015Comparison of epoxy- and cyclocarbonate-functionalised vinyl ethers in radical copolymerisation with chlorotrifluoroethylenecitations
- 2015Copolymerization of fluorinetd monomers in the Presence of a Persistent Radical
- 2015New semi-IPN PEMFC membranes composed ofcrosslinked fluorinated copolymer bearing triazolegroups and sPEEK for operation at low relativehumiditycitations
- 2015Dispersion of Silica Nanoparticles Bearing Perfluorohexyl Units into Fluorinated Copolymerscitations
- 2014Anhydrous proton motion study by solid state NMR spectroscopy in novel PEMFC blend membranes composed of fluorinated copolymer bearing 1,2,4- triazole functional groups and sPEEKcitations
- 2014From glycidyl carbonate to hydroxyurethane sidegroups in alternating fluorinated copolymerscitations
- 2014Unique Difference in Transition Temperature of Two Similar Fluorinated Side Chain Polymers Forming Hexatic Smectic Phase: Poly{2-(perfluorooctyl)ethyl acrylate} and Poly{2- (perfluorooctyl)ethyl vinyl ether}citations
- 2014(Co)polymers of Chlorotrifluoroethylene: Synthesis, Properties, and Applicationscitations
- 2014Radical Copolymerization of Chlorotrifluoroethylene with 4-Bromo-3,3,4,4-tetrafluorobut-1-enecitations
- 2014Photocatalytic Activity of Vinylidene fluoride-Containing Copolymers/anatase Titanium Oxide/Silica Nanocompositescitations
- 2014Original blend membranes of partially fluorinated copolymers bearing azole functions with sulfonated PEEK for PEMFC operating at low relative humidity
- 2013Synthesis and characterizations of alternating co- and terpolymers based on vinyl ethers and chlorotrifluoroethylenecitations
- 2013Where is the glass transition temperature of poly(tetrafluoroethylene)? A new approach by dynamic rheometry and mechanical testscitations
- 2013First RAFT/MADIX radical copolymerization of tert-butyl 2-trifluoromethacrylate with vinylidene fluoride controlled by xanthatecitations
- 2013Novel Method to Assess the Molecular Weights of Fluoropolymers by Radical Copolymerization of Vinylidene Fluoride with Various Fluorinated Comonomers Initiated by a Persistent Radicalcitations
- 2013Advances in the (co)polymerization of 2-trifluoromethacrylic acid and alkyl 2-trifluoro methacrylatescitations
- 2013Structural analysis and surface wettability of a novel alternated vinylidene cyanide with fluorinated vinyl ether copolymercitations
- 2013Radical Copolymerization of Acrylonitrile with 2,2,2-Trifluoroethyl Acrylate for Dielectric Materials: Structure and Characterizationcitations
- 2013Polyelectrolyte/fluorinated polymer interpenetrating polymer networks as fuel cell membranecitations
- 2013An efficient method to synthesize vinyl ethers (VEs) that bear various halogenated or functional groups and their radical copolymerization with chlorotrifluoroethylene (CTFE) to yield functional poly(VE-alt-CTFE) alternated copolymerscitations
- 2013Conventional Radical Polymerization and Iodine-Transfer Polymerization of 40-Nonafluorobutyl styrene: Surface and Thermal Characterizations of the Resulting Poly(fluorostyrene)scitations
- 2012Design and Photonic Properties of Novel Fluorinated Copolymers Bearing Phthalocyanine Side Groupscitations
- 2012Kinetics of RAFT homopolymerisation of vinylbenzyl chloride in the presence of xanthate or trithiocarbonatecitations
- 2012Novel Source of Trifluoromethyl Radical as Efficient Initiator for the Polymerization of Vinylidene Fluoridecitations
- 2012Fluorinated (Co)Polymers: Synthesis, Properties, and Applicationscitations
- 2012An Innovative Trifluoromethyl Radical from Persistent Radical as Efficient Initiator for the Radical Copolymerization of Vinylidene Fluoride with tert-butyl α-Trifluoromethacrylate
- 2012Synthesis and Characterizations of Novel Proton-Conducting Fluoropolymer Electrolyte Membranes Based on Poly(vinylidene fluoride-ter-hexafluoropropylene-ter-α-trifluoromethacrylic acid) Terpolymers Grafted by Aryl Sulfonic Acids†citations
- 2012Fluoroalkyl end-capped vinyltrimethoxysilane oligomer/anatase titanium oxide 3 nanocomposites possessing photocatalytic activity even after calcination at 1000 Ccitations
- 2011First Amphiphilic Poly(vinylidene fluoride-co-3,3,3-^trifluoropropene)-b-oligo(vinyl alcohol) Block Copolymers as Potential Nonpersistent Fluorosurfactants from Radical Polymerization Controlled by Xanthatecitations
- 2011Polymeric materials as anion-exchange membranes for alkaline fuel cellscitations
- 2011Synthesis and Characterization of Functional Fluorinated Telomerscitations
- 2011Recent Advances on the synthesis of Fluorofunctional Polymers for Fuel Cell Membranes
- 2011Synthesis and characterisation of novel fluorinated polymers bearing pendant imidazole groups and blend membranes: New materials for PEMFC operating at low relative humiditycitations
- 2011Recent Advances on the Synthesis of Fluorinated Copolymers for Fuel cell Membranes
- 2011Conversion of Poly(ethylene-alt-tetrafluoroethylene) Copolymers into Polytetrafluoroethylene by Direct Fluorination: A Convenient Approach to Access New Properties at the ETFE Surfacecitations
- 2011Tailored Covalent Grafting of Hexafluoropropylene Oxide Oligomers onto Silica Nanoparticles: Toward Thermally Stable, Hydrophobic, and Oleophobic Nanocompositescitations
- 2011Recent Advances on Original Synthesis of Fluorinated Copolymers for Fuel cell Membranes
- 2011Iodine Transfer Terpolymerization of Vinylidene Fluoride, alpha-Trifluoromethacrylic Acid and Hexafluoropropylene for Exceptional Thermostable Fluoropolymers/Silica Nanocompositescitations
- 2010Telechelic Diiodopoly(VDF-co-PMVE) Copolymers by Iodine Transfer Copolymerization of Vinylidene Fluoride (VDF) with Perfluoromethyl vinyl ether (PMVE)citations
- 2010Controlled radical Copolymerization of Fluoromonomers. Applications to the Synthesis of High Performance Elastomers
- 2010Radical Copolymerization of alpha,β-Difluoroacrylic Acid with Vinylidene Fluoride.citations
- 2010Original Fluorinated Copolymers Achieved by Both Azide/Alkyne “Click” Reaction and Hay Coupling from Tetrafluoroethylene Telomerscitations
- 2010Synthesis and Properties of New Fluorinated Polymers Bearing Pendant Imidazole Groups for Fuel Cell Membranes Operating Over a Broad Relative Humidity Rangecitations
- 2010Grafting Polymerization of Styrene onto Alternating terpolymers Based on Chlorotrifluoroethylene, Hexafluoropropylene, and Vinyl Ethers, and Their Modification into lonomers Bearing Ammonium Side-Groupscitations
- 2010Unexpected Alternating Radical Copolymerization of Chlorotrifluoroethylene with 3-Isopropenyl-a,a'-dimethylbenzyl Isocyanatecitations
- 2010Free-radical copolymerization of 2,2,2-trifluoroethyl methacrylate and 2,2,2-trichloroethyl alpha-fluoroacrylate: Synthesis, kinetics of copolymerization and characterizationcitations
- 2009Free Radical Copolymerization of a-Fluoroacrylates for Optical Materials: Synthesis and Characterizationcitations
- 2009TUTORIAL: FLUOROOLEFIN POLYMERIZATION TOWARDS FUEL CELL
- 2009Iodine Transfer Copolymerization of Vinylidene Fluoride and a-Trifluoromethacrylic Acid in Emulsion Process Without Any Surfactantscitations
- 2009Dielectric behaviour of copolymers based on 2,2,2-trifluoroethyl methacrylate and cyano co-monomerscitations
- 2009Multinuclear Magnetic Resonance and DFT Studies of the Poly(chlorotrifluoroethylene-alt-ethyl vinyl ether) Copolymerscitations
- 2009Multinuclear Magnetic Resonance and DFT Studies of the Poly(chlorotrifluoroethylene-alt-ethyl vinyl ether) Copolymerscitations
- 2009Fluorinated hydroxytelechelic polybutadiene as additive in cationic photopolymerization of an epoxy resincitations
- 2008Copolymères comprenant des groupes phosphonates et/ou acides phosphoniques utilisables pour constituer des membranes de piles à combustible
- 2008Radical Terpolymerization of 1,1,2-Trifluoro-2-pentafluorosulfanylethylene and Pentafluorosulfanylethylene in the Presence of Vinylidene Fluoride and Hexafluoropropylene by Iodine Transfer Polymerizationcitations
- 2008Free Radical Copolymerization of 2,2,2-Trifluoroethyl a-Fluoroacrylate and tert-Butyl a-Trifluoromethylacrylate: Thermal and Optical Properties of the Copolymerscitations
- 2007FLUOROSULPHONATED ELASTOMERS WITH LOW GLASS TRANSITION BASED OF VINYLIDENE FLUORIDE
- 2007Self Emulsion Radical Copolymerization of Vinylidene Fluoride with a-Trifluoromethacrylic acid. Application to Original Fuel Cell Membranes
- 2006Kinetics of the iodine transfer polymerization of vinylidene fluoridecitations
- 2006COMBUSTION AND THERMAL DECOMPOSITION OF FLUORINATED POLYMERScitations
- 2006Poly(vinylidene fluoride)-b-poly(styrene) Block Copolymers by Iodine Transfer Polymerization (ITP): Synthesis, Characterization, and Kinetics of ITPcitations
- 2006Radical copolymerization of 2,2,2-trifluoroethyl methacrylate with cyano compounds for dielectric materials: Synthesis and characterizationcitations
- 2006Crosslinking and characterization of commercially available poly(VDF-co-HFP) copolymers with 2,4,4-trimethyl-1,6-hexanediaminecitations
- 2005Iodine Transfer Polymerization (ITP) of Vinylidene Fluoride (VDF). Influence of the Defect of VDF Chaining on the Control of ITPcitations
- 2005Radical solution copolymerisation of vinylidene fluoride with hexafluoropropenecitations
- 2004First MALDI-TOF Mass Spectrometry of Vinylidene Fluoride Telomers Endowed with Low Defect Chaining
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article
Multinuclear Magnetic Resonance and DFT Studies of the Poly(chlorotrifluoroethylene-alt-ethyl vinyl ether) Copolymers
Abstract
Chlorotrifluoroethylene (CTFE) and ethyl vinyl ether (EVE) were reacted under radical conditions to produce the poly(CTFE-co-EVE) alternating copolymer, and a full C-13, H-1, and F-19 NMR structural interpretation is offered. All spectra were characterized by broad signals resulting from the overlapping of different chemical shifts. This observation was rationalized by considering a complex mixture of diastereomerically related Compounds, hence allowing an average assignment to be determined. A density functional theory (DFT) Computational study of the isotropic magnetic shieldings with the GIAO and CSGT methods was performed to explore the diasteriomeric relationships between the single building blocks and their mutual influences along the polymer chain. The calculated results totally support the assignment of the experimental chemical shifts of two diasteriomeric sets of resonances indicating chiral center inversion, and not spin-spin J coupling interactions, as the main cause of spectral complexity.