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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Larsen, Niels Bent
Technical University of Denmark
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (22/22 displayed)
- 2023Contrast-enhanced ultrasound imaging using capacitive micromachined ultrasonic transducerscitations
- 2022High Resolution Dual Material Stereolithography for Monolithic Microdevicescitations
- 2022Immobilization of Active Antibodies at Polymer Melt Surfaces during Injection Molding
- 20213D printed calibration micro-phantoms for super-resolution ultrasound imaging validationcitations
- 20193D Printed Calibration Micro-phantoms for Validation of Super-Resolution Ultrasound Imagingcitations
- 2015Hydrogen silsesquioxane mold coatings for improved replication of nanopatterns by injection moldingcitations
- 2013Injection molding of high aspect ratio sub-100 nm nanostructurescitations
- 2013Designing CAF-adjuvanted dry powder vaccinescitations
- 2012A Platform for Functional Conductive Polymers
- 2012Micropatterning of Functional Conductive Polymers with Multiple Surface Chemistries in Registercitations
- 2011Enhanced transduction of photonic crystal dye lasers for gas sensing via swelling polymer filmcitations
- 2011Injection molded nanofluidic chips: Fabrication method and functional tests using single-molecule DNA experimentscitations
- 2011Microwave assisted click chemistry on a conductive polymer filmcitations
- 2011Selective gas sensing for photonic crystal lasers
- 2010Fast prototyping of injection molded polymer microfluidic chipscitations
- 2010Nanostructures for all-polymer microfluidic systemscitations
- 2010“Electro-Click” on Conducting Polymer Films
- 2008Novel polymer coatings based on plasma polymerized 2-methoxyethyl acrylate
- 2008Conductive Polymer Functionalization by Click Chemistrycitations
- 2007Micropatterning of a stretchable conductive polymer using inkjet printing and agarose stampingcitations
- 2006On the Injection Molding of Nanostructured Polymer Surfacescitations
- 2001Surface morphology of PS-PDMS diblock copolymer filmscitations
Places of action
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article
Conductive Polymer Functionalization by Click Chemistry
Abstract
Click chemistry is used to obtain new conductive polymer films based on poly(3,4-ethylenedioxythiophene) (PEDOT) from a new azide functional monomer. Postpolymerization, 1,3-dipolar cycloadditions in DMF, using a catalyst system of CUS04 and sodium ascorbate, and different alkynes are performed to functionalize films of PEDOT-N3 and copolymers prepared from EDOT-N3 and 3,4-ethylenedioxythiophene (EDOT). This approach enables new functionalities on PEDOT that could otherwise not withstand the polymerization conditions. Reactions on the thin polymer films have been optimized using an alkynated fluorophore, with reaction times of '"'-'20 h. The applicability of the method is illustrated by coupling of two other alkynes: a short chain fluorocarbon and a MPEG 5000 to the conductive polymer; this alters the advancing water contact angle of the surface by +20° and -20°/-25°, respectively. The targeted chemical surface modifications have been verified by X-ray photoelectron spectroscopy analysis.