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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Boudet, Nathalie
Processes and Engineering in Mechanics and Materials
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (24/24 displayed)
- 2023Influence of the Ge content on the lithiation process of crystalline Si 1− x Ge x nanoparticle-based anodes for Li-ion batteriescitations
- 2022Relationship between atomic structure and excellent glass forming ability in Pd 42.5 Ni 7.5 Cu 30 P 20 metallic glasscitations
- 2022Coupling between elastic strains and phase transition in dense pure zirconia polycrystalscitations
- 2022Relationship between atomic structure and excellent glass forming ability in Pd42.5Ni7.5Cu30P20 metallic glasscitations
- 2021Detailed structural analysis of amorphous Pd40Cu40P20: Comparison with the metallic glass Pd40Ni40P20 from the viewpoint of glass forming abilitycitations
- 2021Detailed structural analysis of amorphous Pd 40 Cu 40 P 20 :Comparison with the metallic glass Pd 40 Ni 40 P 20 from the viewpoint of glass forming abilitycitations
- 2020Prelithiation of silicon/graphite composite anodes: Benefits and mechanisms for long-lasting Li-Ion batteriescitations
- 2019Advanced Non-Destructive in Situ Characterization of Metals with the French Collaborating Research Group D2AM/BM02 Beamline at the European Synchrotron Radiation Facilitycitations
- 2019Advanced Non-Destructive in Situ Characterization of Metals with the French Collaborating Research Group D2AM/BM02 Beamline at the European Synchrotron Radiation Facilitycitations
- 2019Heterogeneous Nanostructural Aging of Fuel Cell Ionomer Revealed by Operando SAXScitations
- 2019Partial structure investigation of the traditional bulk metallic glass Pd40Ni40P20citations
- 2019Partial structure investigation of the traditional bulk metallic glass Pd40Ni40 P20citations
- 2018In situ Synchrotron X-Ray diffraction study of high-temperature stress relaxation in chromia scales containing the reactive element yttriumcitations
- 2017Strains in thermally growing Cr2O3 films measured in situ using synchrotron X-rayscitations
- 2016Tuning the conductivity type in a room temperature magnetic oxide: Ni-doped Ga0.6Fe1.4O3 thin filmscitations
- 2016Reaction of Ni film with In0.53Ga0.47As: Phase formation and texturecitations
- 2016Determination of the cationic distribution in oxidic thin films by resonant X-ray diffraction: the magnetoelectric compound Ga2-xFexO3. Supporting information
- 2016Self-organized arrays of dislocations in thin smectic liquid crystal filmscitations
- 2016Self-organized arrays of dislocations in thin smectic liquid crystal filmscitations
- 2014Probing Self-Assembly of Cylindrical Morphology Block Copolymer Using in Situ and ex Situ Grazing Incidence Small-Angle X-ray Scattering: The Attractive Case of Graphoepitaxycitations
- 2012Key experimental information on intermediate-range atomic structures in amorphous Ge2Sb2Te5 phase change materialcitations
- 2012Anomalous x-ray diffraction measurements of long-range order in (001)-textured L1(0) FePtCu thin filmscitations
- 2011Microstructural mapping of C60 phase transformation into disordered graphite at high pressure, using X-ray diffraction microtomographycitations
- 2007Development of structural order during supercooling of a fragile oxide meltcitations
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article
Probing Self-Assembly of Cylindrical Morphology Block Copolymer Using in Situ and ex Situ Grazing Incidence Small-Angle X-ray Scattering: The Attractive Case of Graphoepitaxy
Abstract
The self-assembly of polystyrene-block-poly(methyl methacrylate) (PS-b-PMMA) copolymer (BCP) films, leading to hexagonal arrays of perpendicular PMMA cylinders in a PS matrix, and its ordering kinetics were investigated using ex situ and in situ grazing incidence small-angle X-ray scattering (GISAXS). The ex situ measurements have provided accurate information about the structural changes in self-assembled BCP films with multiple processing parameters (PMMA removal process, film thickness, annealing treatment). Such structural information proves essential since BCP films are envisioned as template materials for density multiplication in nanolithography. Moreover, the temperature-dependent GISAXS measurements indicate that phase-separation starts around 140 degrees C and annealing up to 240 degrees C is required to form homogeneous self-assembled films within the short baking times required by industry. Furthermore, the guiding effect of an hydrogen silsesquioxane (HSQ) line grating commensurable with the polymer period on self-assembly (the so-called graphoepitaxy approach) was studied on silicon wafers presenting jointly patterned and unpatterned areas. When the line grating is aligned with the direction of the incident X-ray beam, the GISAXS pattern of the graphoepitaxial BCP film reveals the formation of a single domain extended over large areas. In contrast, the pattern of the BCP film self-assembled on the neighbor unpatterned area, comes from randomly oriented domains. Besides, the line grating does not only guide the BCP self-assembly, but as shown, also increases its ordering kinetics, demonstrating the high potentialities of graphoepitaxy.