| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Wurm, Frederik R.
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (42/42 displayed)
- 2024Helical Polyamines
- 2023Copolymerizing Lignin for Tuned Properties of 3D-Printed PEG-Based Photopolymerscitations
- 2023Biodegradable polyphosphoester micelles act as both background-free 31P magnetic resonance imaging agents and drug nanocarrierscitations
- 2023Water-soluble polyphosphonate-based bottlebrush copolymers via aqueous ring-opening metathesis polymerizationcitations
- 2023The microstructure of polyphosphoesters controls polymer hydrolysis kinetics from minutes to yearscitations
- 2023Real-time 31P NMR reveals different gradient strengths in polyphosphoester copolymers as potential MRI-traceable nanomaterialscitations
- 2023Reversible acetalization of cellulosecitations
- 2023Towards more homogeneous character in 3D printed photopolymers by the addition of nanofillerscitations
- 2022Real-Time 1H and 31P NMR spectroscopy of the copolymerization of cyclic phosphoesters and trimethylene carbonate reveals transesterification from gradient to random copolymerscitations
- 2021Green synthesis and characterization of poly(glycerol-azelaic acid) and its nanocomposites for applications in regenerative medicinecitations
- 2021Facile template preparation of novel electroactive scaffold composed of polypyrrole-coated poly(glycerol-sebacate-urethane) for tissue engineering applicationscitations
- 2021RNA-inspired intramolecular transesterification accelerates the hydrolysis of polyethylene-like polyphosphoesterscitations
- 2021Display of hidden properties of flexible aerogel based on bacterial cellulose/polyaniline nanocomposites with helping of multiscale modelingcitations
- 2020Intrinsic flame retardant phosphonate-based vitrimers as a recyclable alternative for commodity polymers in composite materialscitations
- 2020Developing antibacterial superhydrophobic coatings based on polydimethylsiloxane/silver phosphate nanocompositescitations
- 2020Controlling the biodegradation rates of poly(globalide-co-ε-caprolactone) copolymers by post polymerization modificationcitations
- 2019Matrix matterscitations
- 2019Supercooled Water Drops Do Not Freeze During Impact on Hybrid Janus Particle-Based Surfacescitations
- 2019Copolymerization of Cyclic Phosphonate and Lactide: Synthetic Strategies toward Control of Amphiphilic Microstructurecitations
- 2018Surface-attached poly(phosphoester)-hydrogels with benzophenone groupscitations
- 2018Temperature responsive poly(phosphonate) copolymerscitations
- 2017Poly(alkyl ethylene phosphonate)scitations
- 2017Acid-labile surfactants based on poly(ethyleneglycol), carbon dioxide and propylene oxidecitations
- 2016Fast ultrasound assisted synthesis of chitosan-based magnetite nanocomposites as a modified electrode sensorcitations
- 2016Sequence-Controlled Polymers via Simultaneous Living Anionic Copolymerization of Competing Monomerscitations
- 2016Acid-Labile Amphiphilic PEO-b-PPO-b-PEO Copolymerscitations
- 2016Processing and adjusting the hydrophilicity of poly(oxymethylene) (co)polymerscitations
- 2016Poly(phosphorodiamidate)s by Olefin Metathesis Polymerization with Precise Degradationcitations
- 2016Side-chain poly(phosphoramidate)scitations
- 2015Vinyl ferrocenyl glycidyl ethercitations
- 2014Ferrocene-containing multifunctional polyetherscitations
- 2014Stabilization of nanoparticles synthesized by miniemulsion polymerization using "green" amino-acid based surfactantscitations
- 2013Enlarging the toolboxcitations
- 2013Microstructure analysis of biocompatible phosphoester copolymerscitations
- 2013Ferrocenyl glycidyl ethercitations
- 2013Unsaturated poly(phosphoester)s via ring-opening metathesis polymerizationcitations
- 2012Hyperbranched Polymerscitations
- 2011Rapid access to polyfunctional lipids with complex architecture via oxyanionic ring-opening polymerizationcitations
- 2011PEG-based multifunctional polyethers with highly reactive vinyl-ether side chains for click-type functionalizationcitations
- 2010"Functional poly(ethylene glycol)"citations
- 2008Carbanions on tap - Living anionic polymerization in a microstructured reactorcitations
- 2008Ionic polymerizations in microstructured reactors
Places of action
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article
Ferrocene-containing multifunctional polyethers
Abstract
<p>Ferrocenyl glycidyl ether (fcGE) and allyl glycidyl ether (AGE) are copolymerized via living anionic ring-opening polymerization to generate polyfunctional copolymers with molecular weights up to 40-300 g/mol and low molecular weight dispersities (M<sub>w</sub>/M<sub>n</sub> < 1.18). Copolymerizations were carried out in bulk at 100 °C and unexpectedly found to proceed without any isomerization of the allyl double bonds. The copolymerization behavior of fcGE and AGE was monitored by in situ quantitative <sup>13</sup>C NMR kinetic measurements in bulk, evidencing the formation of random copolymers under these conditions, showing no gradient of comonomer incorporation. The redox-active behavior of the copolymers and homopolymers of fcGE was studied by cyclic voltammetry (CV). In order to demonstrate possible postmodification reactions, the random copolymers were modified with N-acetyl-l-cysteine methyl ester via a thiol-ene addition. All polymers have furthermore been characterized by <sup>1</sup>H NMR spectroscopy, DOSY <sup>1</sup>H NMR spectroscopy, size exclusion chromatography (SEC), and MALDI-ToF mass spectrometry.</p>