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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Zhang, Kai
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (17/17 displayed)
- 2024A fully kinetic phase diagram-coupled multicomponent columnar-to-equiaxed grain transition model with an application to additive manufacturingcitations
- 2024Pore evolution mechanisms during directed energy deposition additive manufacturing
- 2024Unravelling dynamic recrystallisation in a microalloyed steel during rapid high temperature deformation using synchrotron X-rayscitations
- 2023Record field in a 10 mm-period bulk high-temperature superconducting undulatorcitations
- 2023The Ground State of Epitaxial Germanene on Ag(111)citations
- 2022MACHINE LEARNING METHODS FOR UNESCO CHINESE HERITAGE: COMPLEXITY AND COMPARISONScitations
- 2021Enhanced CDM model accounting of stress triaxiality and Lode angle for ductile damage prediction in metal formingcitations
- 2021Deformation Texture Evolution in Flat Profile AlMgSi Extrusions: Experiments, FEM, and Crystal Plasticity Modelingcitations
- 2020Growth of germanium-silver surface alloys followed by in situ scanning tunneling microscopy: Absence of germanene formationcitations
- 2019Assessment of advanced Taylor models, the Taylor factor and yield-surface exponent for FCC metalscitations
- 2018Through thickness variations of deformation texture in round profile extrusions of 6063-type aluminium alloy: Experiments, FEM and crystal plasticity modellingcitations
- 2017How Bound and Free Fatty Acids in Cellulose Films Impact Nonspecific Protein Adsorptioncitations
- 2017How Bound and Free Fatty Acids in Cellulose Films Impact Nonspecific Protein Adsorptioncitations
- 2014Ultra-light nanocomposite aerogels of bacterial cellulose and reduced graphene oxide for specific absorption and separation of organic liquidscitations
- 2012Solid-State Spectroscopic Characterization of α-Chitins Deacetylated in Homogeneous Solutionscitations
- 2012Donor-acceptor conjugated polymers based on p- and o-benzodifuranone and thiophene derivativescitations
- 2012Analysis of carboxylate groups in oxidized never-dried cellulose II catalyzed by TEMPO and 4-acetamide-TEMPOcitations
Places of action
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article
Donor-acceptor conjugated polymers based on p- and o-benzodifuranone and thiophene derivatives
Abstract
<p>A series of pi-conjugated polymers consisting of bis-EDOT or bis-EDTT units and p- or o-diphenylbenzodifuranones have been prepared electrochemically. The monomers and polymers were investigated using UV/vis absorption spectroscopy and cyclic voltammetry. The monomers were synthesized from 3,4-ethylenedioxythien-2-yl or 3,4-ethylenedithiathien-2-yl trimethylstannane and 3,7-bis(4-bromophenyl)benzo[1,2-b:4,5-b']difuran-2,6-dione or 3,6-bis(4-bromophenyl)benzo[1,2-b:6,5-b']difuran-2,7-dione using Stile coupling. The polymers exhibit broad absorption bands, and strong donor-acceptor characteristics with very small band gaps (in a range from 0.40 to 1.20 eV). Electrochemically grown polymer thin films exhibit reversible behavior under oxidative and reductive conditions. Under reduction, the polymer films show color changes from dark to almost transparent.</p>