| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Marin, Guy
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (29/29 displayed)
- 2022Upcycling the carbon emissions from the steel industry into chemicals using three metal oxide loopscitations
- 2022Decarbonisation of steel mill gases in an energy-neutral chemical looping processcitations
- 2021Microstructured ZrO2 coating of iron oxide for enhanced CO2 conversioncitations
- 2020Hierarchical Fe-modified MgAl2O4 as Ni-catalyst support for methane dry reformingcitations
- 2020FeO controls the sintering of iron-based oxygen carriers in chemical looping CO2 conversioncitations
- 2019The relevance of multi‐injection and temperature profiles to design multi‐phase reactive processing of polyolefinscitations
- 2019Pressure-induced deactivation of core-shell nanomaterials for catalyst assisted chemical loopingcitations
- 2019Carbon capture and utilization in the steel industry : challenges and opportunities for chemical engineeringcitations
- 2019Carbon capture and utilization in the steel industry : challenges and opportunities for chemical engineeringcitations
- 2019Fe2O3-MgAl2O4 for CO production from CO2 : Mössbauer spectroscopy and in situ X-ray diffractioncitations
- 2018Ni nanoparticles and the Kirkendall effect in dry reforming of methanecitations
- 2017Controlling the stability of a Fe-Ni reforming catalyst : structural organization of the active componentscitations
- 2017How penultimate monomer unit effects and initiator choice influence ICAR ATRP of n-butyl acrylate and methyl methacrylatecitations
- 2017CO production from CO2 via reverse water–gas shift reaction performed in a chemical looping mode : kinetics on modified iron oxidecitations
- 2017Size- and composition-controlled Pt–Sn bimetallic nanoparticles prepared by atomic layer depositioncitations
- 2016Atomic layer deposition route to tailor nanoalloys of noble and non-noble metalscitations
- 2016Hydrogen and carbon monoxide production by chemical looping over iron-aluminium oxidescitations
- 2016Deactivation study of Fe2O3−CeO2 during redox cycles for CO production from CO2citations
- 2016Kinetics of multi-step redox processes by time-resolved In situ X-ray diffractioncitations
- 2015Mg-Fe-Al-O for advanced CO2 to CO conversion: carbon monoxide yield vs. oxygen storage capacitycitations
- 2015Model-based design of the polymer microstructure : bridging the gap between polymer chemistry and engineering
- 2015Model-based design of the polymer microstructure: bridging the gap between polymer chemistry and engineeringcitations
- 2014Fed-batch control and visualization of monomer sequences of individual ICAR ATRP gradient copolymer chainscitations
- 2014Delivering a modifying element to metal nanoparticles via support: Pt-Ga alloying during the reduction of Pt/Mg(Al,Ga)Ox catalysts and its effects on propane dehydrogenationcitations
- 2012Linear gradient quality of ATRP copolymerscitations
- 2011Fundamental kinetic modelling of reactions in nanoporous materials: from free carbenium ion chemistry towards extreme shape selectivity
- 2010Atom transfer radical polymerization of isobornyl acrylate: a kinetic modeling studycitations
- 2010Theoretical study of the thermal decomposition of dimethyl disulfidecitations
- 2007Effect of microstructure and crystallinity on the photocatalytic activity of TiO2 thin films deposited by dc magnetron sputtering
Places of action
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article
Atom transfer radical polymerization of isobornyl acrylate: a kinetic modeling study
Abstract
A detailed kinetic modeling study of the atom transfer radical polymerization (ATRP) of isobornyl acrylate (iBoA) is presented. This study combines a detailed reaction scheme with a systematic approach to account for diffusional limitations. Calculated values for diffusion coefficients and the Williams-Landel-Ferry parameters for poly(iBoA) are based on rheological measurements. A good agreement with experimental data is obtained for the polymerization rate, average chain length, and polydispersity index in conditions ranging from 323 to 348 K for targeted chain lengths varying from 50 to 100 and initial activator/deactivator concentrations between 10-50/0-2.5 mol m(-3). In these conditions, beta C-scission reactions are insignificant and backbiting reactions result in a slight decrease of the polymerization rate and level of control at high conversions only. Termination is subject to diffusional limitations during the whole ATRP, while diffusional limitations on deactivation cannot be neglected at higher conversion. Diffusional limitations are shown to be codetermined by the evolution of the chain length distribution of both the end-chain and mid-chain macromolecular species.