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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Li, Dan
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (8/8 displayed)
- 2024Counterintuitive Trend of Intrusion Pressure with Temperature in the Hydrophobic Cu2(tebpz) MOFcitations
- 2024Counterintuitive Trend of Intrusion Pressure with Temperature in the Hydrophobic Cu<sub>2</sub>(tebpz) MOFcitations
- 2024Mild-Temperature Supercritical Water Confined in Hydrophobic Metal–Organic Frameworkscitations
- 2019Dynamic resistance and rational design of railway prestressed concrete sleepers
- 2018Dynamic capacity reduction of railway prestressed concrete sleepers due to surface abrasions considering the effects of strain rate and prestressing lossescitations
- 2017Impact Capacity Reduction in Railway Prestressed Concrete Sleepers with Surface Abrasionscitations
- 2017Influence of surface abrasion on creep and shrinkage of railway prestressed concrete sleeperscitations
- 2002Impact of Fluorination and Side-Chain Length on Poly(methylpropenoxyalkylsiloxane) and Poly(alkyl methacrylate) Solubility in Supercritical Carbon Dioxidecitations
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article
Impact of Fluorination and Side-Chain Length on Poly(methylpropenoxyalkylsiloxane) and Poly(alkyl methacrylate) Solubility in Supercritical Carbon Dioxide
Abstract
A great deal of interest has been generated within the past few decades on supercritical fluid technology applied to polymerization processes, polymer purification and fractionation processes, and solution coatings and powder formation processes. A critical issue for each of these potential applications is the determination of polymer solubility in supercritical carbon dioxide, a highly preferred processing solvent. There exists a fair amount of experimental data on solubility of polymers and copolymers in CO<sub>2</sub> from which it is possible to obtain insight into the properties of the polymer that control solubility. It is now well-known that fluorinating a polymer enhances its solubility in supercritical CO<sub>2</sub>; however, it is also accepted that polymer polarity and backbone flexibility also have a strong influence on the temperatures and pressures needed to dissolve a polymer in supercritical CO. In addition, it has been shown that fluorinating an alkyl side chain improves polymer solubility, and likewise, it has been shown that polymer solubility decreases significantly as the length of a nonfluorinated alkyl side chain is increased.