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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Huinink, Hp Henk
Eindhoven University of Technology
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (17/17 displayed)
- 2023Polymeric stabilization of salt hydrates for thermochemical energy storagecitations
- 2022Impact of polymeric stabilisers on the reaction kinetics of SrBr2citations
- 2021Encapsulation of salt hydrates by polymer coatings for low-temperature heat storage applicationscitations
- 2020Stabilization of K2CO3 in vermiculite for thermochemical energy storagecitations
- 2020Core-Shell Encapsulation of Salt Hydrates into Mesoporous Silica Shells for Thermochemical Energy Storagecitations
- 2017Transport of a water-soluble polymer during drying of a model porous mediacitations
- 2017Transport of a water-soluble polymer during drying of a model porous media
- 2013NMR study of the microstructures and water-polymer interactions in cross-linked polyurethane coatingscitations
- 2013NMR study of the microstructures and water-polymer interactions in cross-linked polyurethane coatingscitations
- 2013Water permeability of pigmented waterborne coatingscitations
- 2013Water permeability of pigmented waterborne coatingscitations
- 2012Quantitative water uptake study in thin nylon-6 films with NMR imagingcitations
- 2006Influence of catalyst type on the curing process and network structure of alkyd coatingscitations
- 2006Influence of catalyst type on the curing process and network structure of alkyd coatingscitations
- 2006Mass transfer and gelation in sandstone cores of a novel water shut off chemicalcitations
- 2001Pore size distribution from hydrogen and sodium NMR using the transverse relaxationcitations
- 2001Surface-induced transitions in thin films of asymmetric diblock copolymerscitations
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article
Surface-induced transitions in thin films of asymmetric diblock copolymers
Abstract
A dynamic density functional theory for polymeric systems has been used to investigate the influence of surface fields on the morphology of thin films of asymmetric diblock copolymers, which form cylinders in a bulk system. We have found that noncylindrical structures become stable when one of the blocks is strongly attracted by the surfaces. When the interaction between the surface and the polymer was increased, two transitions occur: (a) from parallel oriented cylinders to parallel oriented perforated lamellae (C ¿ CL) and (b) from this perforated lamellae to lamellae (CL ¿ L). It has also been observed that the microstructure becomes much more sensitive to the film thickness in the case where the surfaces strongly attract one of the polymer blocks. The influence of the surfaces seems to be limited to a region with a size of the order of one domain-domain distance.