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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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De Wolf, Frits A.
Wageningen University & Research
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (5/5 displayed)
- 2016Enhanced stiffness of silk-like fibers by loop formation in the corona leads to stronger gelscitations
- 2014Synergistic stiffening in double-fiber networkscitations
- 2013Disulfide bond-stabilized physical gels of an asymmetric collagen-inspired telechelic protein polymercitations
- 2009Polypeptide nanoribbon hydrogels assembled through multiple supramolecular interactionscitations
- 2009Precision gels from collagen-inspired triblock copolymerscitations
Places of action
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article
Polypeptide nanoribbon hydrogels assembled through multiple supramolecular interactions
Abstract
We investigated the formation of nanoribbon hydrogels in a mixed system of zinc ions, bis(ligand)s, and triblock peptide copolymers. Using a combination of experimental techniques: dynamic light scattering, cryo-transmission electron microscopy, small-angle X-ray scattering and circular dichroism, we arrived at a model for the formation of nanoribbon hydrogels in which well-defined nanoribbons are formed out of multiple supramolecular interactions: (1) metal coordination that yields supramolecular polyelectrolytes; (2) electrostatic complexation between the supramolecular polyelectrolytes and the oppositely charged blocks of the peptide copolymers; (3) hydrogen bond and (4) hydrophobic interactions that support the secondary and ternary structure of the ribbons; (5) van der Waals interactions that enable bundling of the ribbons.