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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Buck, Manfred
University of St Andrews
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (16/16 displayed)
- 2022Coordination-controlled electrodeposition of palladium/copper thin films onto a pyridine-terminated self-assembled monolayer
- 2021Porous Honeycomb Self-Assembled Monolayerscitations
- 2021Porous honeycomb self-assembled monolayers:tripodal adsorption and hidden chirality of carboxylate anchored triptycenes on Agcitations
- 2021Porous honeycomb self-assembled monolayers : tripodal adsorption and hidden chirality of carboxylate anchored triptycenes on Agcitations
- 2020Coordination controlled electrodeposition and patterning of layers of palladium/copper nanoparticles on top of a self-assembled monolayercitations
- 2019Coordination controlled electrodeposition and patterning of layers of palladium/copper nanoparticles on top of a self-assembled monolayercitations
- 2012Redox mediation enabled by immobilised centres in the pores of a metal-organic framework grown by liquid phase epitaxycitations
- 2011Electrodeposition of Palladium onto a Pyridine-Terminated Self-Assembled Monolayercitations
- 2010Organic Mono layers, Networks, Electrochemistry: A Toolbox for the Nanoscale
- 2009Self-Assembly of a Pyridine-Terminated Thiol Monolayer on Au(111)citations
- 2008On the role of extrinsic and intrinsic defects in the underpotential deposition of Cu on thiol-modified Au(111) electrodescitations
- 2007Influence of molecular structure on phase transitions: A study of self-assembled monolayers of 2-(aryl)-ethane thiolscitations
- 2005Replicative generation of metal microstructures by template-directed electrometallizationcitations
- 2003Pronounced Odd-Even Changes in the Molecular Arrangement and Packing Density of Biphenyl-Based Thiol SAMs: A Combined STM and LEED Studycitations
- 2002Optical properties of a light-emitting polymer directly patterned by soft lithographycitations
- 2000Solvation of oligo(ethylene glycol)-terminated self-assembled monolayers studied by vibrational sum frequency spectroscopycitations
Places of action
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article
Self-Assembly of a Pyridine-Terminated Thiol Monolayer on Au(111)
Abstract
<p>Self-assembled monolayers (SAMs) of 3-(4-pyridine-4-yl-phenyl)-propane-1- thiol (PyP3) on Au(111)/mica have been studied by scanning tunneling microscopy (SIM), polarization-modulated infrared reflection absorption spectroscopy (PM-IRRAS), high-resolution X-ray photoemission spectroscopy (HRXPS), and near-edge X-ray absorption fine structure (NEXAFS) spectroscopy. The quality of the SAM is found to be strongly dependent on the solvent. Substantial gold corrosion is observed if pure ethanol is used. In contrast, highly ordered and densely packed SAMs are formed from acetonitrile or a KOH/ethanol mixture. The structure is described by a 2√3 × √3 unit cell with the aromatic moiety oriented nearly perpendicular to the surface. The PyP3 films form with the pyridine moiety deprotonated. Variation of pH allows reversible protonation without measurable damage of the SAM.</p>