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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Velikov, Krassimir Petkov
University of Amsterdam
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (13/13 displayed)
- 2024Thermoresponsive oil-continuous gels based on double-interpenetrating colloidal-particle networkscitations
- 2023Towards a constitutive relation for emulsions exhibiting a yield stresscitations
- 2023Influence of thickeners (microfibrillated cellulose, starch, xanthan gum) on rheological, tribological and sensory properties of low-fat mayonnaisescitations
- 2022Ethyl cellulose nanoparticles as stabilizers for Pickering emulsionscitations
- 2022Elastic reinforcement and yielding of starch-filled lipid gelscitations
- 2022Unravelling discolouration caused by iron-flavonoid interactionscitations
- 2020Multivalent ion-induced re-entrant transition of carboxylated cellulose nanofibrils and its influence on nanomaterials' propertiescitations
- 2019Biobased Cellulose Nanofibril–Oil Composite Films for Active Edible Barrierscitations
- 2019Cellulose microfibril networks in hydrolysed soy protein isolate solutionscitations
- 2017Revealing and Quantifying the Three-Dimensional Nano- and Microscale Structures in Self-Assembled Cellulose Microfibrils in Dispersionscitations
- 2015Microstructure and rheology of microfibril-polymer networkscitations
- 2014Phase transitions in cellulose microfibril dispersions by high-energy mechanical deagglomerationcitations
- 2003Synthesis and characterization of large colloidal silver particlescitations
Places of action
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article
Phase transitions in cellulose microfibril dispersions by high-energy mechanical deagglomeration
Abstract
<p>It is shown that dispersions of cellulose microfibrils display gel-sol and direct gel-colloidal liquid crystalline structure transitions. This is achieved by applying high-energy mechanical deagglomeration to bacterial cellulose (BC) networks in the presence of sodium carboxymethyl cellulose (CMC). At high CMC content adsorption of the polymer leads to a significant increase in the potential. The resulting apparent phase diagram shows transitions from aggregates to single microfibril dispersions with increasing the CMC/BC weight ratio at low microfibril concentrations. At higher concentrations, liquid crystalline ordering was observed and the microstructure becomes more homogeneous with increasing the CMC content. The observed liquid crystalline ordering was found to be reminiscent of nematic gels. Applying deagglomeration in the presence of CMC, thus, transitions the system from aggregates and gels to dispersions of single microfibrils and nematic gel-type structures.</p>