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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Weidner, Tobias
Aarhus University
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (29/29 displayed)
- 2022Peptide Orientation at Emulsion Nanointerfaces Dramatically Different from Flat Surfacescitations
- 2021Windowless detection geometry for sum frequency scattering spectroscopy in the C-D and amide i regionscitations
- 2021Insects use lubricants to minimize friction and wear in leg jointscitations
- 2020Role of Surface Chemistry in the Superhydrophobicity of the Springtail Orchesella cincta (Insecta:Collembola)citations
- 2020Lasalocid Acid Antibiotic at a Membrane Surface Probed by Sum Frequency Generation Spectroscopycitations
- 2018Structure of von Willebrand factor A1 on polystyrene determined from experimental and calculated sum frequency generation spectracitations
- 2018The surface chemistry of iron oxide nanocrystalscitations
- 2018Effect of Internal Heteroatoms on Level Alignment at Metal/Molecular Monolayer/Si Interfacescitations
- 2016Kinetically Controlled Sequential Growth of Surface-Grafted Chiral Supramolecular Copolymerscitations
- 2016Differential surface activation of the A1 domain of von Willebrand factorcitations
- 2016Functionalization of nanocrystalline diamond films with phthalocyaninescitations
- 2015Multiscale Effects of Interfacial Polymer Confinement in Silica Nanocompositescitations
- 2013Effects of self-assembled monolayer structural order, surface homogeneity and surface energy on pentacene morphology and thin film transistor device performancecitations
- 2013SFG analysis of surface bound proteinscitations
- 2013Covalently attached organic monolayers onto silicon carbide from 1-alkynescitations
- 2013Molecular suction padscitations
- 2012Probing the orientation of electrostatically immobilized protein G B1 by time-of-flight secondary ion spectrometry, sum frequency generation, and near-edge X-ray adsorption fine structure spectroscopycitations
- 2012Zwitterionic dithiocarboxylates derived from N-heterocyclic carbenescitations
- 2012Bottom-contact small-molecule n-type organic field effect transistors achieved via simultaneous modification of electrode and dielectric surfacescitations
- 2012Solid-state densification of spun-cast self-assembled monolayers for use in ultra-thin hybrid dielectricscitations
- 2011Simultaneous modification of bottom-contact electrode and dielectric surfaces for organic thin-film transistors through single-component spin-cast monolayerscitations
- 2011Probing albumin adsorption onto calcium phosphates by x-ray photoelectron spectroscopy and time-of-flight secondary ion mass spectrometrycitations
- 2011Characterization of poly(sodium styrene sulfonate) thin films grafted from functionalized titanium surfacescitations
- 2010Probing the orientation of surface-immobilized protein G B1 using ToF-SIMS, sum frequency generation, and NEXAFS spectroscopycitations
- 2010Multi-technique Characterization of Adsorbed Peptide and Protein Orientationcitations
- 2010Structure and Order of Phosphonic Acid-Based Self-Assembled Monolayers on Si(100)citations
- 2010Effect of the phenyl ring orientation in the polystyrene buffer layer on the performance of pentacene thin-film transistorscitations
- 2009Self-Assembly of a Pyridine-Terminated Thiol Monolayer on Au(111)citations
- 2009Amide or Aminecitations
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article
Covalently attached organic monolayers onto silicon carbide from 1-alkynes
Abstract
<p>In order to achieve improved tribological and wear properties at semiconductor interfaces, we have investigated the thermal grafting of both alkylated and fluorine-containing ((C<sub>x</sub>F<sub>2x+1</sub>)-(CH <sub>2</sub>)<sub>n</sub>-) 1-alkynes and 1-alkenes onto silicon carbide (SiC). The resulting monolayers display static water contact angles up to 120. The chemical composition of the covalently bound monolayers was studied by X-ray photoelectron spectroscopy (XPS), infrared reflection-absorption spectroscopy (IRRAS), and near-edge X-ray absorption fine structure (NEXAFS) spectroscopy. These techniques indicate the presence of acetal groups at the organic-inorganic interface of alkyne-modified SiC surfaces. The tribological properties of the resulting organic monolayers with fluorinated or nonfluorinated end groups were explored using atomic force microscopy (AFM). It was found that the fluorinated monolayers exhibit a significant reduction of adhesion forces, friction forces, and wear resistance compared with non-fluorinated molecular coatings and especially bare SiC substrates. The successful combination of hydrophobicity and excellent tribological properties makes these strongly bound, fluorinated monolayers promising candidates for application as a thin film coating in high-performance microelectronic devices.</p>