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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Keddie, Joseph
University of Surrey
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (9/9 displayed)
- 2019Sphere-to-worm morphological transitions and size changes through thiol–para-fluoro core modification of PISA-made nano-objects
- 2018Colloidal Polymer Composites: Are Nano-Fillers Always Better for Improving Mechanical Properties?citations
- 2018Enhanced Water Barrier Properties of Surfactant-Free Polymer Films Obtained by MacroRAFT-Mediated Emulsion Polymerizationcitations
- 2017Hydrophilic MacroRAFT-Mediated Emulsion Polymerization: Synthesis of Latexes for Cross-linked and Surfactant-Free Filmscitations
- 2017Tightening of Gelatin Chemically Cross-linked Networks Assisted by Physical Gelationcitations
- 2016Explanations for Water Whitening in Secondary Dispersion and Emulsion Polymer Filmscitations
- 2012Simultaneous Free‐Radical and Addition Miniemulsion Polymerization: Effect of the Chain Transfer Agent on the Microstructure of Polyurethane‐Acrylic Pressure‐Sensitive Adhesivescitations
- 2011Simultaneous free radical and addition miniemulsion polymerization: Effect of the diol on the microstructure of polyurethane-acrylic pressure-sensitive adhesivescitations
- 2011Waterborne polyurethane-acrylic hybrid nanoparticles by miniemulsion polymerization: applications in pressure-sensitive adhesives.citations
Places of action
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article
Waterborne polyurethane-acrylic hybrid nanoparticles by miniemulsion polymerization: applications in pressure-sensitive adhesives.
Abstract
Waterborne polyurethane−acrylic hybrid nanoparticles for application as pressure-sensitive adhesives (PSAs) were prepared by one-step miniemulsion polymerization. The addition of polyurethane to a standard waterborne acrylic formulation results in a large increase in the cohesive strength and hence a much higher shear holding time (greater than seven weeks at room temperature), which is a very desirable characteristic for PSAs. However, with the increase in cohesion, there is a decrease in the relative viscous component, and hence there is a decrease in the tack energy. The presence of a small concentration of methyl methacrylate (MMA) in the acrylic copolymer led to phase separation within the particles and created a hemispherical morphology. The tack energy was particularly low in the hybrid containing MMA because of the effects of lower energy dissipation and greater cross-linking. These results highlight the great sensitivity of the viscoelastic and adhesive properties to the details of the polymer ne...