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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Dreas-Wlodarczak, Agnieszka
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article
Immobilization of Zinc Porphyrin Complexes on Pyridine-Functionalized Glass Surfaces
Abstract
In order to immobilize sublimable and fluorescent dye molecules on transparent surfaces for the detection of far field molecular interference experiments, we investigate the potential of pyridine-functionalized glass substrates as coordination sites for the zinc complex of tetraphenylporphyrin (ZnTPP)). Borosilicate glass is functionalized with 4-(6-(ethoxydimethylsilyl)hexyloxy)pyridine in order to cover the glass surface with pyridine subunits. ZnTPP molecules are deposited by sublimation through mechanical masks of various sizes in a high-vacuum chamber. The resulting micropatterns are analyzed using epifluorescence microscopy which also allows us to define a measure for the quality of molecular immobilization. We observe a reduced mobility and an increased efficiency for the trapping of ZnTPP on pyridine-functionalized surfaces.